铜催化叠氮化物、炔烃和硒的串联多组分反应：二唑基二硒醚的合成
Copper-Catalyzed Cascade Multicomponent Reaction of Azides, Alkynes, and Selenium: Synthesis of Ditriazolyl Diselenides.
作者信息
Sun Bo-Xun, Wang Xu-Nan, Fan Tai-Gang, Hou Yu-Jian, Shen Yun-Tao, Li Ya-Min
机构信息
Faculty of Life Science and Technology, Kunming University of Science and Technology, Kunming 650500, P. R. China.
出版信息
J Org Chem. 2023 Apr 7;88(7):4528-4535. doi: 10.1021/acs.joc.2c03102. Epub 2023 Mar 13.
PMID:36913662
Abstract
A copper-catalyzed cascade multicomponent reaction for synthesizing ditriazolyl diselenides from azides, terminal alkynes, and elemental selenium has been developed. The present reaction features utilizing readily available and stable reagents, high atom-economy, and mild reaction conditions. A possible mechanism is proposed.
摘要
已开发出一种铜催化的级联多组分反应，用于由叠氮化物、末端炔烃和元素硒合成二唑基二硒醚。该反应具有使用易得且稳定的试剂、高原子经济性和温和的反应条件等特点。提出了一种可能的机理。
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