Key Laboratory of Unconventional Oil and Gas Development, China University of Petroleum (East China), Qingdao, 266580, China.
College of Petroleum Engineering, China University of Petroleum (East China), Qingdao, 266580, China.
Sci Rep. 2023 Mar 13;13(1):4157. doi: 10.1038/s41598-023-30614-y.
Reducing the heat loss in wellbore is the key for efficient development of geothermal resource. It is a reliable solution to establish a long-term stable wellbore with good thermal insulation through cementing. In this paper, the cement-based composite thermal insulation material was prepared by using cement as the cementing material, hollow glass beads, foaming agent and stabilizer as main raw materials, and other conventional admixtures. Foams and hollow glass beads can introduce gas with low thermal conductivity into cement, so as to improve the thermal insulation of composite material. Foams are produced by chemical forming process, using foaming agent, which is prepared according electrochemistry and thermodynamics, and the foam stabilizer helps foam distribute in cement slurry stably and uniformly. 10-13% hollow glass beads can significantly reduce the thermal conductivity of hardened cement, without significant adverse effects on the rheology and strength of the material. The thermal conductivity of the composite thermal insulation material can be as low as 0.2998 W·(m·K), which is 62% lower than that of conventional cement, while the compressive strength is 6.10 MPa, meeting the engineering requirement. A thermal-conductivity prediction method is proposed correspondingly based on Maxwell model, and the prediction error of the newly established model is within 2%. This research can provide technical support for efficient development of geothermal resources.
减少井筒热损失是地热资源高效开发的关键。通过固井建立长期稳定、隔热性能良好的井筒是一种可靠的解决方案。本文以水泥为胶凝材料,空心玻璃微珠、发泡剂和稳定剂为主要原料,辅以其他常规外加剂,制备了水泥基复合保温材料。泡沫和空心玻璃微珠可以将导热系数低的气体引入水泥中,从而提高复合材料的保温性能。泡沫是通过化学成泡过程产生的,使用根据电化学和热力学制备的发泡剂,泡沫稳定剂有助于泡沫在水泥浆中稳定均匀地分布。添加 10-13%的空心玻璃微珠可以显著降低水泥基材料的导热系数,而对材料的流变性和强度没有明显的不利影响。复合保温材料的导热系数低至 0.2998 W·(m·K),比常规水泥低 62%,而抗压强度为 6.10 MPa,满足工程要求。相应地提出了一种基于 Maxwell 模型的导热系数预测方法,新建立模型的预测误差在 2%以内。本研究可为地热资源的高效开发提供技术支持。