Key Laboratory of Molecule Synthesis and, Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China.
State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, 361005, China.
Chem Asian J. 2023 May 2;18(9):e202300122. doi: 10.1002/asia.202300122. Epub 2023 Mar 27.
Electrochemical dearomative spirocyclization serves as a green and sustainable approach to convert the flat, two-dimension aromatic feedstock into the value-added three-dimension spirocyclic architectures. This review highlights the recent advances, emphasizes mechanistic discussions, and showcases synthetic applications of this emerging versatile and powerful transformation.
电化学去芳构化螺环化反应为将平坦的二维芳香原料转化为增值的三维螺环结构提供了一种绿色可持续的方法。本综述重点介绍了这一新兴多功能且强大转化的最新进展,强调了机理讨论,并展示了其在合成中的应用。