Department of Chemistry, Soongsil University, Seoul, 06978, Republic of Korea.
Department of Physics and Integrative Institute of Basic Sciences, Soongsil University, Seoul, 06978, Republic of Korea.
Chem Commun (Camb). 2023 Mar 30;59(27):4040-4043. doi: 10.1039/d2cc06797h.
Cu(II)-based zeolitic imidazolates (Cu-ZIFs), Cu-ZIF-gis and -rho, formulated as Cu(nIm) (nIm = 2-nitroimidazolate) have highly-flattened tetrahedral coordination geometry. Cu-ZIF-gis has 2.4 Å cylindrical pores that can adsorb H gas, and Cu-ZIF-rho has 19.8 Å cages with a BET surface area of 1320 m g.
基于铜（II）的沸石咪唑酯（Cu-ZIFs），Cu-ZIF-gis 和 -rho，被设计为 Cu（nIm）（nIm = 2-硝基咪唑），具有高度扁平化的四面体配位几何形状。Cu-ZIF-gis 具有 2.4Å 的圆柱形孔，可以吸附 H 气体，而 Cu-ZIF-rho 具有 19.8Å 的笼状结构，BET 表面积为 1320m2/g。
