Improving the electrochemical energy conversion of solid oxide fuel cells through the interface effect in LaSrCoFeO-BaTiO electrolyte.

Herein, we present a heterostructure electrolyte with considerable potential for application in low-temperature solid oxide fuel cells (LT-SOFCs). Heterostructure electrolytes are advantageous because the multiphase interfaces in their heterostructures are superior for ion conduction than for bulk conduction. Most previous studies on heterostructure electrolytes explained the influence of interfacial parameters on ion conduction in terms of the space charge zones and lattice mismatch, neglecting the characterization of the interface. In this study, a series of heterostructure electrolytes comprising LaSrCoFeO (LSCF) and BaTiO (BTO) with different composition ratios was developed. Further, the lattice mismatch due to thermal stress in this system was evaluated by thermal expansion and electron energy loss spectroscopy (EELS) analyses. Results indicated that 7LSCF-3BTO produced the narrowest interface and the most surface oxygen vacancies, suggesting that the stress generated by thermal expansion increased the density of the interface. The cell with the optimal 7LSCF-3BTO composition delivered a peak power density of 910mW cm and an open circuit voltage of 1.07 V at 550 °C. The heterojunction effect was studied to elucidate the prevention of short circuiting in the LSCF-BTO cell, considering the Femi level and barrier energy height. This study provides novel ideas for the design of electrolytes for LT-SOFCs from the interface perspective.