Department of Chemistry, Sacred Heart College (Autonomous), Kochi, Kerala Pin-682013, India.
Department of Chemistry, Sacred Heart College (Autonomous), Kochi, Kerala Pin-682013, India.
Carbohydr Polym. 2023 Jun 15;310:120700. doi: 10.1016/j.carbpol.2023.120700. Epub 2023 Feb 17.
This research highlights the synergistic use of carbon black (CB) and chitin nanofibers (CHNFs) for developing green tyres for the first time. The CHNFs (12-30 nm) were prepared from chitin powder with the help of steam explosion and mild oxalic acid hydrolysis. The CHNFs were uniformly dispersed in natural rubber (NR) latex, dried, and mixed with CB in a two-roll mill to form NR/CB/CHNF composites. The NR/CB/CHNF composite at 1 phr CHNF loading exhibited tensile and tear strengths that were about 47 and 160 % greater than the NR-Neat, respectively. The dynamic mechanical analysis showed that the loss tangent (tan δ) at 60 °C was 50 % lower for the NR/CB/CHNF 1.0 composite than for the NR/CB50 composite. The study succeeded in developing a new green tyre tread formulation that would be helpful for attaining sustainability and a circular economy.
本研究首次强调了炭黑(CB)和甲壳素纳米纤维(CHNFs)的协同使用,用于开发绿色轮胎。CHNFs(12-30nm)是通过蒸汽爆炸和温和的草酸水解从甲壳素粉末中制备的。CHNFs 均匀分散在天然橡胶(NR)胶乳中,干燥后与 CB 在双辊机中混合,形成 NR/CB/CHNF 复合材料。在 1 phr CHNF 负载下的 NR/CB/CHNF 复合材料的拉伸强度和撕裂强度分别比 NR-Neat 提高了约 47%和 160%。动态力学分析表明,NR/CB/CHNF 1.0 复合材料在 60°C 时的损耗角正切(tanδ)比 NR/CB50 复合材料低 50%。该研究成功开发了一种新的绿色轮胎胎面配方,这将有助于实现可持续性和循环经济。