Department of Chemistry, Sacred Heart College (Autonomous), Kochi, Kerala, 682013, India; Department of Applied Chemistry, Cochin University of Science and Technology (CUSAT), Kerala, 682022, India.
Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology (CUSAT), Kerala, 682022, India.
Carbohydr Polym. 2020 Feb 15;230:115620. doi: 10.1016/j.carbpol.2019.115620. Epub 2019 Nov 13.
The effect of replacing carbon black (CB) by rice husk derived type-I nanocellulose (RHNC) in natural rubber vulcanization is presented in this study. The synthesized RHNC was characterized using various analytical techniques like FTIR, XRD, SEM, TEM, DLS, TGA etc. The cure characteristics, mechanical, technological, thermal, barrier and dynamic mechanical properties of the composites were analysed. The mechanical properties of the NR composites containing 30 wt% of CB are comparable with the composite containing 25 wt% of CB and 5 wt% of RHNC. The DMA studies show that the loss tangent (tan δ) at 60 °C is lower for the composite containing 5 wt% of RHNC and 25 wt% CB compared to the composite containing 30 wt% CB. This shows that RHNC can impart low rolling resistance, which is a crucial parameter for green tire applications.
本研究介绍了用稻壳衍生的 I 型纳米纤维素(RHNC)替代炭黑(CB)对天然橡胶硫化的影响。采用傅里叶变换红外光谱(FTIR)、X 射线衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、动态光散射(DLS)、热重分析(TGA)等多种分析技术对合成的 RHNC 进行了表征。分析了复合材料的硫化特性、力学性能、加工性能、热性能、阻隔性能和动态力学性能。含有 30wt%CB 的 NR 复合材料的力学性能可与含有 25wt%CB 和 5wt%RHNC 的复合材料相媲美。DMA 研究表明,与含有 30wt%CB 的复合材料相比,含有 5wt%RHNC 和 25wt%CB 的复合材料在 60°C 时的损耗角正切(tanδ)较低。这表明 RHNC 可以赋予低滚动阻力,这是绿色轮胎应用的关键参数。