• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

阳离子烷基链长度对具有较低临界溶解温度的甲基丙烯酸3-磺丙酯基提余液溶质的影响。

Effect of cation alkyl chain length on 3-sulfopropylmethacrylate-based draw solutes having lower critical solution temperature.

作者信息

Moon Jihyeon, Kang Hyo

机构信息

BK-21 Four Graduate Program, Department of Chemical Engineering, Dong-A University 37 Nakdong-Daero 550 Beon-gil, Saha-gu Busan 49315 Republic of Korea

出版信息

RSC Adv. 2023 Mar 14;13(12):8291-8298. doi: 10.1039/d2ra08068k. eCollection 2023 Mar 8.

DOI:10.1039/d2ra08068k
PMID:36926002
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10011973/
Abstract

We investigated the effect of change in alkyl chain length of cation in tributylalkylphosphonium 3-sulfopropyl methacrylate ([P][CS], # = 4, 6, and 8) ionic liquids (ILs) on their osmolality and recovery properties as the draw solute in the forward osmosis (FO) process. The ILs aqueous solutions exhibited a characteristic of the lower critical solution temperature (LCST)-type phase separation, which allowed for the easy recovery of the draw solute or clean water from the diluted draw solution. The LCSTs of 31, 26, 22, and 18 °C were obtained from 2.5, 5.0, 7.5, and 10.0 wt% aqueous solutions of [P][CS]. When deionized water, 2000 ppm NaCl solution, and 10.0 wt% orange juice aqueous solution were used as feed solution, the water fluxes of the aqueous [P][CS] solutions were approximately 4.49, 3.87, and 1.55 LMH, respectively, in the active layer facing the draw solution mode at 7.5 wt% of draw solution. This study demonstrates the applicability of a thermoresponsive ionic structure material as a draw solute for the FO process.

摘要

我们研究了甲基丙烯酸3-磺丙酯三丁基烷基鏻盐（[P][CS]，# = 4、6和8）离子液体（ILs）中阳离子烷基链长度的变化对其作为正向渗透（FO）过程中汲取溶质的渗透压和回收性能的影响。ILs水溶液表现出较低临界溶液温度（LCST）型相分离的特性，这使得能够从稀释的汲取溶液中轻松回收汲取溶质或净化水。[P][CS]的2.5、5.0、7.5和10.0 wt%水溶液的LCST分别为31、26、22和18 °C。当使用去离子水、2000 ppm NaCl溶液和10.0 wt%橙汁水溶液作为进料溶液时，在7.5 wt%汲取溶液的面向汲取溶液模式的活性层中，[P][CS]水溶液的水通量分别约为4.49、3.87和1.55 LMH。本研究证明了热响应离子结构材料作为FO过程汲取溶质的适用性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/5042fd81e0e9/d2ra08068k-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/e24bd74eccdd/d2ra08068k-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/eece8a504dc2/d2ra08068k-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/fcbbfd88e018/d2ra08068k-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/ea086e57e2d1/d2ra08068k-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/6fedd41a3268/d2ra08068k-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/994a94554eba/d2ra08068k-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/cb0504f7cfac/d2ra08068k-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/5042fd81e0e9/d2ra08068k-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/e24bd74eccdd/d2ra08068k-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/eece8a504dc2/d2ra08068k-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/fcbbfd88e018/d2ra08068k-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/ea086e57e2d1/d2ra08068k-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/6fedd41a3268/d2ra08068k-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/994a94554eba/d2ra08068k-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/cb0504f7cfac/d2ra08068k-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/58ea/10011973/5042fd81e0e9/d2ra08068k-f8.jpg

相似文献

1
Effect of cation alkyl chain length on 3-sulfopropylmethacrylate-based draw solutes having lower critical solution temperature.阳离子烷基链长度对具有较低临界溶解温度的甲基丙烯酸3-磺丙酯基提余液溶质的影响。
RSC Adv. 2023 Mar 14;13(12):8291-8298. doi: 10.1039/d2ra08068k. eCollection 2023 Mar 8.
2
Anion Effect on Forward Osmosis Performance of Tetrabutylphosphonium-Based Draw Solute Having a Lower Critical Solution Temperature.阴离子对具有较低临界溶液温度的四丁基鏻基汲取溶质的正向渗透性能的影响
Membranes (Basel). 2023 Feb 8;13(2):211. doi: 10.3390/membranes13020211.
3
Effects of the Structure of Benzenesulfonate-Based Draw Solutes on the Forward Osmosis Process.基于苯磺酸盐的汲取溶质结构对正向渗透过程的影响。
Membranes (Basel). 2022 Oct 29;12(11):1067. doi: 10.3390/membranes12111067.
4
Thermoresponsive Ionic Liquid with Different Cation-Anion Pairs as Draw Solutes in Forward Osmosis.作为正向渗透汲取液的具有不同阴阳离子对的温敏离子液体。
Molecules. 2022 Dec 13;27(24):8869. doi: 10.3390/molecules27248869.
5
Effect of the Alkyl Chain Length on Assessment as Thermo-Responsive Draw Solutes for Forward Osmosis.烷基链长度对作为正渗透热响应性拉溶质评估的影响。
ACS Omega. 2022 Nov 2;7(45):41508-41518. doi: 10.1021/acsomega.2c05279. eCollection 2022 Nov 15.
6
Influence of the anionic structure and central atom of a cation on the properties of LCST-type draw solutes for forward osmosis.阳离子的阴离子结构和中心原子对用于正向渗透的最低临界溶液温度型脱除溶质性能的影响。
RSC Adv. 2022 Oct 13;12(45):29405-29413. doi: 10.1039/d2ra05131a. eCollection 2022 Oct 11.
7
Polymer Having Dicationic Structure in Dumbbell Shape for Forward Osmosis Process.用于正向渗透过程的哑铃形双阳离子结构聚合物。
Polymers (Basel). 2019 Mar 26;11(3):571. doi: 10.3390/polym11030571.
8
Ferric and cobaltous hydroacid complexes for forward osmosis (FO) processes.用于正向渗透（FO）过程的铁和钴氢酸配合物。
Water Res. 2014 Jul 1;58:230-8. doi: 10.1016/j.watres.2014.03.024. Epub 2014 Apr 3.
9
Synthesis and Application of Organic Phosphonate Salts as Draw Solutes in Forward Osmosis for Oil-Water Separation.有机膦酸盐盐作为正向渗透中油水分离的汲取剂的合成与应用。
Environ Sci Technol. 2016 Nov 1;50(21):12022-12029. doi: 10.1021/acs.est.6b02953. Epub 2016 Oct 13.
10
Thermo-responsive draw solute for forward osmosis process; poly(ionic liquid) having lower critical solution temperature characteristics.用于正渗透过程的热响应性拉拔溶质；具有较低临界溶液温度特性的聚（离子液体）
RSC Adv. 2019 Sep 18;9(51):29493-29501. doi: 10.1039/c9ra04020j.

本文引用的文献

1
Imidazolium Triflate Ionic Liquids' Capacitance-Potential Relationships and Transport Properties Affected by Cation Chain Lengths.三氟甲磺酸咪唑鎓离子液体的电容-电位关系及受阳离子链长度影响的传输性质
ACS Meas Sci Au. 2021 Aug 10;1(3):117-130. doi: 10.1021/acsmeasuresciau.1c00015. eCollection 2021 Dec 15.
2
Origin of low melting point of ionic liquids: dominant role of entropy.离子液体低熔点的起源：熵的主导作用。
Chem Sci. 2022 Jun 8;13(25):7560-7565. doi: 10.1039/d2sc02342c. eCollection 2022 Jun 29.
3
Ionic Liquids and Water: Hydrophobicity vs. Hydrophilicity.
离子液体与水：疏水性与亲水性。
Molecules. 2021 Nov 26;26(23):7159. doi: 10.3390/molecules26237159.
4
pH-Responsive Polyoxometalates that Achieve Efficient Wastewater Reclamation and Source Recovery via Forward Osmosis.通过正向渗透实现高效废水回收和源头回收的 pH 响应型多金属氧酸盐。
Environ Sci Technol. 2021 Sep 21;55(18):12664-12671. doi: 10.1021/acs.est.1c04245. Epub 2021 Sep 8.
5
Evaluating the economic impact of water scarcity in a changing world.评估变化世界中水资源短缺的经济影响。
Nat Commun. 2021 Mar 26;12(1):1915. doi: 10.1038/s41467-021-22194-0.
6
Desalination of brackish water by gelatin-coated magnetite nanoparticles as a novel draw solute in forward osmosis process.基于明胶包覆磁铁矿纳米粒子的新型汲取剂用于正向渗透过程淡化苦咸水。
Environ Technol. 2021 Jul;42(18):2885-2895. doi: 10.1080/09593330.2020.1717642. Epub 2020 Jan 29.
7
Odd-even effect on the formation of aqueous biphasic systems formed by 1-alkyl-3-methylimidazolium chloride ionic liquids and salts.由 1-烷基-3-甲基咪唑氯盐离子液体和盐形成的双水相体系的形成中的奇偶效应。
J Chem Phys. 2018 May 21;148(19). doi: 10.1063/1.5012020. Epub 2018 Apr 10.
8
Forward Osmosis Application in Manufacturing Industries: A Short Review.正向渗透在制造业中的应用：简要综述。
Membranes (Basel). 2018 Jul 23;8(3):47. doi: 10.3390/membranes8030047.
9
Pharmaceutical concentration using organic solvent forward osmosis for solvent recovery.采用有机溶剂正向渗透的药物浓缩及溶剂回收。
Nat Commun. 2018 Apr 12;9(1):1426. doi: 10.1038/s41467-018-03612-2.
10
Viscosity, Conductivity, and Electrochemical Property of Dicyanamide Ionic Liquids.双氰胺离子液体的粘度、电导率及电化学性质
Front Chem. 2018 Mar 15;6:59. doi: 10.3389/fchem.2018.00059. eCollection 2018.