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蟹壳衍生的SnS/C和FeS/C碳复合材料作为高性能钠离子电池的阳极

Crab Shell-Derived SnS/C and FeS/C Carbon Composites as Anodes for High-Performance Sodium-Ion Batteries.

作者信息

Chen Yun, Zhao Yue, Liu Hongbin, Ma Tingli

机构信息

Medical Engineering and Technology Research Center, School of Radiology, Shandong First Medical University, Shandong Academy of Medical Sciences, Taian 271000, China.

Graduate School of Life Science and Systems Engineering, Kyushu Institute of Technology, 2-4 Hibikino, Wakamatsu, Kitakyushu 808-0196, Japan.

出版信息

ACS Omega. 2023 Feb 28;8(10):9145-9153. doi: 10.1021/acsomega.2c06429. eCollection 2023 Mar 14.

DOI:10.1021/acsomega.2c06429
PMID:36936300
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10018519/
Abstract

The demand for energy storage devices has increased significantly, and the sustainable development of lithium-ion batteries is limited by scarce lithium resources. Therefore, alternative sodium-ion batteries which are rich in resource may become more competitive in the future market. In this work, we synthesized low-cost SnS/C and FeS/C anode materials of sodium-ion batteries which used waste crab shells as biomass carbon precursor. The SnS nanosheet and FeS nanosphere structures are deposited on the crab shell-derived carbon through simple hydrothermal reaction. Due to the coexistence of transition metal dichalcogenides (TMDs) and crab-derived biomass carbon, the anode material has excellent cycle stability and rate performance. SnS/C and FeS/C deliver capacities of 535.4 and 479 mA h g at the current density of 0.1 A g, respectively. This study explored an effective and economical strategy to use biomass and TMDs to construct high-performance sodium-ion batteries.

摘要

对储能设备的需求显著增加,而锂离子电池的可持续发展受到锂资源稀缺的限制。因此,资源丰富的钠离子电池在未来市场可能会更具竞争力。在这项工作中,我们以废弃蟹壳作为生物质碳前驱体,合成了低成本的钠离子电池SnS/C和FeS/C负极材料。通过简单的水热反应,将SnS纳米片和FeS纳米球结构沉积在蟹壳衍生的碳上。由于过渡金属二硫属化物(TMDs)和蟹衍生生物质碳的共存,负极材料具有优异的循环稳定性和倍率性能。在0.1 A g的电流密度下,SnS/C和FeS/C的容量分别为535.4和479 mA h g。本研究探索了一种利用生物质和TMDs构建高性能钠离子电池的有效且经济的策略。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/cd82644ccc61/ao2c06429_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/e65f1786907a/ao2c06429_0002.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/f688bb221111/ao2c06429_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/58510c9d476f/ao2c06429_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/0457f5f0d1af/ao2c06429_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/ba513f4d1964/ao2c06429_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/07defb50af2a/ao2c06429_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/cd82644ccc61/ao2c06429_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/e65f1786907a/ao2c06429_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/a5c315c40f72/ao2c06429_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/afb00ab732e4/ao2c06429_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/06c9f462e1ca/ao2c06429_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/f688bb221111/ao2c06429_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/58510c9d476f/ao2c06429_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/0457f5f0d1af/ao2c06429_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/ba513f4d1964/ao2c06429_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/07defb50af2a/ao2c06429_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4621/10018519/cd82644ccc61/ao2c06429_0011.jpg

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