Thawornprasert Jarernporn, Duangsuwan Wiriya, Somnuk Krit
Department of Mechanical and Mechatronics Engineering, Faculty of Engineering, Prince of Songkla University, Hat Yai, Songkhla, Thailand 90110.
Biotechnology Program, Center of Excellence in Innovative Biotechnology for Sustainable Utilization of Bioresourses, Faculty of Agro-Industry, Prince of Songkla University, Hat Yai, Songkhla, Thailand 90110.
ACS Omega. 2023 Mar 3;8(10):9275-9290. doi: 10.1021/acsomega.2c07537. eCollection 2023 Mar 14.
In this research, the optimum condition for the production of refined crude palm oil methyl ester from refined crude palm oil was investigated using the response surface method via the transesterification reaction in a batch process. The refined crude palm oil was obtained by vacuum distillation of crude palm oil to extract some of the free fatty acids from the oil, providing nutritional benefits and reducing the chemical consumption of the production process. The purity of methyl ester in the refined crude palm oil methyl ester was studied to adjust four independent variables: methanol content (11-23 vol %), concentration of potassium hydroxide (4-12 g/L), stirrer speed (100-500 rpm), and reaction time (9-45 min). The results showed that methyl ester had a purity of 96.91 wt % when synthesized under optimal conditions of 18.2 vol % methanol, a potassium hydroxide concentration of 10.0 g/L, a stirring speed of 380 rpm, and a reaction time of 36.4 min at 60 °C. Refined crude palm oil methyl ester was blended with diesel and ethanol to study the feasibility of using the diesel-refined crude palm oil methyl ester-hydrous ethanol blend in an unmodified diesel engine. A comparative study of fuel properties, emissions, and performance of the diesel-refined crude palm oil methyl ester-ethanol blend was used to assess the feasibility of fuel blends (D40RM50E10, D30RM60E10, D20RM70E10, and D10RM80E10) in diesel engines at various engine speeds and loads. The results showed that the D40RM50E10 blend provided the closest performance to diesel and was environmentally friendly, as it provided nitrogen oxide and carbon monoxide emissions 32 and 55% lower than those with diesel, respectively. The test results indicated that the diesel-refined crude palm oil methyl ester-hydrous ethanol blend is an attractive alternative fuel in agricultural engines that reduces diesel consumption and benefits farmers and rural communities.
在本研究中,采用响应面法,通过间歇式酯交换反应,研究了从精炼粗棕榈油生产精炼粗棕榈油甲酯的最佳条件。精炼粗棕榈油是通过对粗棕榈油进行真空蒸馏以从油中提取一些游离脂肪酸而获得的,这具有营养益处并减少了生产过程中的化学品消耗。研究了精炼粗棕榈油甲酯中甲酯的纯度,以调节四个独立变量:甲醇含量(11 - 23体积%)、氢氧化钾浓度(4 - 12克/升)、搅拌速度(100 - 500转/分钟)和反应时间(9 - 45分钟)。结果表明,在18.2体积%甲醇、氢氧化钾浓度为10.0克/升、搅拌速度为380转/分钟以及60℃下反应36.4分钟的最佳条件下合成时,甲酯的纯度为96.91重量%。将精炼粗棕榈油甲酯与柴油和乙醇混合,以研究在未改装的柴油发动机中使用柴油 - 精炼粗棕榈油甲酯 - 含水乙醇混合物的可行性。对柴油 - 精炼粗棕榈油甲酯 - 乙醇混合物的燃料特性、排放和性能进行了对比研究,以评估燃料混合物(D40RM50E10、D30RM60E10、D20RM70E10和D10RM80E10)在不同发动机转速和负载下在柴油发动机中的可行性。结果表明,D40RM50E10混合物的性能与柴油最接近,并且对环境友好,因为它的氮氧化物和一氧化碳排放量分别比柴油低32%和55%。测试结果表明,柴油 - 精炼粗棕榈油甲酯 - 含水乙醇混合物是农用发动机中有吸引力的替代燃料,可减少柴油消耗,造福农民和农村社区。