Zhao Man, Tang Gongwen, Yang Shuai, Fu Shancan
The Institute of Seawater Desalination and Multipurpose Utilization, MNR (Tianjin) Tianjin 300192 China.
College of Engineering and Technology, Tianjin Agricultural University Tianjin 300384 China
RSC Adv. 2023 Mar 15;13(13):8636-8645. doi: 10.1039/d2ra07889a. eCollection 2023 Mar 14.
The fabrication of dense conductive patterns was achieved by low-temperature sintering of 1-3 μm micron silver flakes. A small amount of 20-50 nm nanosilver particles were added in the gaps of the micron silver flakes. The effects of sintering temperature, holding time and heating rate on the morphological evolution and formation mechanism of the sintered silver pattern were investigated in detail. Interestingly, rapid sintering (RS) can be achieved by removing the heating process from 70 °C up to the sintering temperature. The electrical resistivity of the sintered silver patterns was 10.8 × 10 Ω cm at 140 °C for 30 min under a pressure of 10 MPa. Moreover, the electrical resistivity of the sintered silver pattern for RS for 20 min does not change significantly after 6000 bending cycles. This work provides a new method to fabricate conductive patterns using micron silver flakes with the purpose of promoting the application of silver inks.
通过对1-3微米的微米级银片进行低温烧结来制备致密导电图案。在微米级银片的间隙中添加了少量20-50纳米的纳米银颗粒。详细研究了烧结温度、保温时间和加热速率对烧结银图案的形态演变和形成机制的影响。有趣的是,通过去除从70°C到烧结温度的加热过程可以实现快速烧结(RS)。在10 MPa压力下,于140°C烧结30分钟后,烧结银图案的电阻率为10.8×10Ω·cm。此外,经过6000次弯曲循环后,RS烧结20分钟的烧结银图案的电阻率没有明显变化。这项工作提供了一种使用微米级银片制造导电图案的新方法,旨在促进银墨水的应用。