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高度杂环荧光分子的合成:2-亚氨基-2H-吡喃并[3,2-c]吡啶-5(6H)-酮衍生物

Synthesis of Highly Heterocyclic Fluorescent Molecules: 2-imino-2H-pyrano[3,2-c] Pyridin-5(6H)-ones Derivatives.

作者信息

Mehiaoui Nawel, Hassaine Ridha, Berrichi Amina, Kibou Zahira, Choukchou-Braham Noureddine

机构信息

Laboratory of catalysis and synthesis in organic chemistry, University of Tlemcen, Tlemcen, Algeria.

Centre de Recherche Scientifique et Technique en Analyses Physico-chimiques CRAPC, BP 384, Bou-Ismail, Tipaza, 42004, RP, Algeria.

出版信息

J Fluoresc. 2023 Sep;33(5):1995-2001. doi: 10.1007/s10895-023-03212-4. Epub 2023 Mar 22.

Abstract

New highly fluorescent 2-imino-2H-pyrano[3,2-c]pyridin-5(6H)-onesderivatives were synthesized using a simple route. The present molecules were prepared by two methods with good yield. The structures were characterized by NMRH,  C, and elemental analysis. Also, the effect of solvent and concentration on the fluorescence properties were demonstrated. However, the high fluorescence intensity in the range of 70,000-75,000 a. u. was obtained with a concentration equal to 10 M of prepared molecules. The intensity was influenced also by the molecule structure and solvent.

摘要

通过一条简单的路线合成了新型高荧光性的2-亚氨基-2H-吡喃并[3,2-c]吡啶-5(6H)-酮衍生物。目前的分子通过两种方法制备,产率良好。通过核磁共振氢谱、碳谱和元素分析对结构进行了表征。此外,还展示了溶剂和浓度对荧光性质的影响。然而,当制备的分子浓度等于10⁻⁶M时,获得了70000-75000任意单位范围内的高荧光强度。该强度也受分子结构和溶剂的影响。

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