Evaluating seasonal differences in paraben transformation at two different wastewater treatment plants in Texas and comparing parent compound transformation to byproduct formation.

Parabens are commonly used preservatives that are weakly estrogenic. Wastewater effluent is the greatest contributor to the spread of parabens into rivers and other surface water. While previous studies indicate parabens are well removed in wastewater treatment by way of transformation, not much is known about the paraben transformation products. This study evaluates paraben transformation and release at two different wastewater treatment plants in Texas. Paraben concentrations were quantified for influent and effluent by season and by year at both treatment plants. Both seasonal and annual transformation rates were compared between the two wastewater treatment plants. Compounds were compared to evaluate differences in transformation rates and to determine if decreases in parent product concentrations are correlated to changes in transformation product concentrations. The study took place over one year and evaluated each season. Spring had higher influent concentrations and transformation rates at treatment plant 1, while summer had higher influent concentrations and transformation rates at treatment plant 2. PHBA was present in greatest amounts in influent and effluent at both sites with average yearly influent concentrations at 223.9 pM at plant 1 and 211.4 pM at plant 2. Transformation rates of parent parabens were greater at plant 1 with concentration of all three shorter chained parabens decreasing by over 50% after treatment. Formation of dichlorinated transformation products were greater at plant 1 with concentrations of ClMeP increasing by 1200% after treatment and ClEtP increasing by 940%. While shorter chained parabens generally had a greater transformation rate, no correlations were found between decreases in methyl and ethyl parabens and the formation of their respective dichlorinated transformation products.