Liu Xiaomin, Yang Zhengxian, Li Kang, Briseghella Bruno, Marano Giuseppe Carlo, Xu Jiankun
School of Advanced Manufacturing, Fuzhou University Quanzhou 362200 China
Joint International Research Laboratory of Deterioration and Control of Costal and Marine Infrastructures and Materials, College of Civil Engineering, Fuzhou University Fuzhou 350108 China.
RSC Adv. 2023 Mar 22;13(14):9448-9456. doi: 10.1039/d2ra08281k. eCollection 2023 Mar 20.
In this work, a hybrid Cu-ZnO/g-CN nanocomposite was synthesized and introduced to fabricate photocatalytic cement mortars by internal mixing. The bactericidal properties of the photocatalytic mortars were explored by using , and as a bacteria test strain. The results showed that the Cu-ZnO/g-CN nanocomposite had an enhanced harvesting of visible light energy and exhibited excellent stability during the photocatalytic process, which favored a long-term usage performance. The sterilizing efficiency of the photocatalytic cement mortars improved with an increasing content of Cu-ZnO/g-CN nanocomposites. A possible bactericidal mechanism was proposed based on the active species trapping experiments, verifying that the photogenerated holes (h) and ˙O radicals were the main active species.
在本研究中,合成了一种Cu-ZnO/g-CN混合纳米复合材料,并通过内混法将其引入以制备光催化水泥砂浆。以 、 和 作为细菌测试菌株,探究了光催化砂浆的杀菌性能。结果表明,Cu-ZnO/g-CN纳米复合材料增强了对可见光能量的捕获,并且在光催化过程中表现出优异的稳定性,这有利于长期使用性能。光催化水泥砂浆的杀菌效率随着Cu-ZnO/g-CN纳米复合材料含量的增加而提高。基于活性物种捕获实验提出了一种可能的杀菌机制,证实光生空穴(h)和˙O 自由基是主要的活性物种。