Lou Fengfei, Dong Sujun, Zhu Keyong, Chen Xiaona, Ma Yinwei
School of Aeronautical Science and Engineering, Beihang University, Beijing 100083, China.
Research Department of Airframe Technology, Beijing Institute of Aerospace Technology, Beijing 100074, China.
Gels. 2023 Mar 14;9(3):220. doi: 10.3390/gels9030220.
Due to the extremely high porosity and extremely low density of nano-porous thermal insulation materials, the characteristic size of the pores inside the materials and the characteristic size of the solid skeleton structure are on the nanometer scale, which leads to the obvious nanoscale effect of the heat transfer law inside the aerogel materials. Therefore, the nanoscale heat transfer characteristics inside the aerogel materials and the existing mathematical models for calculating the thermal conductivity of various heat transfer modes at the nanoscale need to be summarized in detail. Moreover, in order to verify the accuracy of the thermal conductivity calculation model of aerogel nano-porous materials, correct experimental data are required to modify the model. Because the medium is involved in radiation heat transfer, the existing test methods have a large error, which brings great difficulties to the design of nano-porous materials. In this paper, the heat transfer mechanism, characterization methods, and test methods of thermal conductivity of nano-porous materials are summarized and discussed. The main contents of this review are as follows. The first part introduces the structural characteristics and specific application environment of aerogel. In the second part, the characteristics of nanoscale heat transfer of aerogel insulation materials are analyzed. In the third part, the characterization methods of thermal conductivity of aerogel insulation materials are summarized. In the fourth part, the test methods of thermal conductivity of aerogel insulation materials are summarized. The fifth part gives a brief conclusion and prospect.
由于纳米多孔绝热材料具有极高的孔隙率和极低的密度,材料内部孔隙的特征尺寸和固体骨架结构的特征尺寸均处于纳米尺度,这使得气凝胶材料内部的传热规律呈现出明显的纳米尺度效应。因此,需要详细总结气凝胶材料内部的纳米尺度传热特性以及现有的用于计算纳米尺度各种传热模式热导率的数学模型。此外,为了验证气凝胶纳米多孔材料热导率计算模型的准确性,需要正确的实验数据来修正该模型。由于介质涉及辐射传热,现有的测试方法误差较大,这给纳米多孔材料的设计带来了很大困难。本文对纳米多孔材料的传热机理、表征方法以及热导率测试方法进行了总结和讨论。本综述的主要内容如下。第一部分介绍了气凝胶的结构特点和具体应用环境。第二部分分析了气凝胶绝热材料的纳米尺度传热特性。第三部分总结了气凝胶绝热材料热导率的表征方法。第四部分总结了气凝胶绝热材料热导率的测试方法。第五部分给出了简要结论与展望。