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从废液晶面板中回收 ITO 浓缩物进行工业规模铟提取的选矿和分类。

Beneficiation and classification of ITO concentrate from waste LCD panel for industrial-scale indium extraction.

机构信息

Materials Science and Chemical Engineering Center, Institute for Advanced Engineering (IAE), Yongin, 17180, Republic of Korea.

Department of Chemical Engineering, Ajou University, Suwon, Republic of Korea.

出版信息

Environ Sci Pollut Res Int. 2023 Aug;30(39):90209-90222. doi: 10.1007/s11356-023-26106-1. Epub 2023 Mar 28.

Abstract

Currently, more than 55% of global indium production is consumed for indium tin oxide (ITO) production because of its excellent display properties mainly driven by demand for flat panel displays (FPDs) or LCDs. At the end of life, the waste LCD flows to the e-waste stream, accounts for 12.5% of the global e-waste, and is forecasted to be increasing progressively. These waste LCDs are potential wealth for indium that poses a threat to the environment. The volume of waste LCD generation is a global as well as national concern from a waste management perspective. Techno-economical recycling of this waste can be a panacea to the challenges associated with the lack of commercial technology and extensive research. Hence, a mass production capable of beneficiation and classification of ITO concentrate from waste LCD panels has been investigated. The mechanical beneficiation process for waste LCDs consists of five steps of operation, i.e., (i) size reduction by shredding by jaw milling, (ii) further size reduction to feed for ball milling, (iii) ball milling, (iv) classification to enrich ITO concentrate, and (v) characterization ITO concentrate and confirmation. The bench-scale process developed is intended to integrate with our indigenously developed dismantling plant (which can handle 5000 tons per annum) to handle separated waste LCD glass for indium recovery. Once scaled up, it can be integrated for continuous operation synchronized with the LCD dismantling plant.

摘要

目前,全球超过 55%的铟产量用于生产铟锡氧化物 (ITO),因为其出色的显示性能主要由平板显示器 (FPD) 或液晶显示器的需求驱动。在使用寿命结束时,废液晶会流入电子废物流,占全球电子废物的 12.5%,预计还会逐步增加。这些废液晶显示器是铟的潜在财富,对环境构成威胁。从废物管理的角度来看,废液晶显示器的产生量是一个全球性和国家性的问题。从技术经济角度对这种废物进行回收利用,可以解决缺乏商业技术和广泛研究带来的挑战。因此,已经研究了从废液晶显示器面板中进行 ITO 浓缩物的选别和分类的大规模生产能力。废液晶的机械选矿过程包括五个操作步骤,即 (i) 通过颚式粉碎进行粉碎以减小尺寸,(ii) 进一步减小尺寸以适合球磨进料,(iii) 球磨,(iv) 进行分类以富集 ITO 浓缩物,以及 (v) 对 ITO 浓缩物进行表征和确认。开发的台架工艺旨在与我们自主开发的拆解工厂(每年可处理 5000 吨)集成,以处理用于铟回收的分离废液晶玻璃。一旦规模化,它可以与液晶显示器拆解工厂同步进行连续操作。

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