Institute of Circular Economy, Beijing University of Technology, Beijing 100124, PR China.
Institute of Circular Economy, Beijing University of Technology, Beijing 100124, PR China.
Waste Manag. 2017 Jun;64:236-243. doi: 10.1016/j.wasman.2017.03.031. Epub 2017 Mar 25.
The tremendous amount of end-of-life liquid crystal displays (LCDs) has become one of the prominent sources of waste electrical and electronic equipment (WEEE) in recent years. Despite the necessity of safe treatment, recycling indium is also a focus of waste LCD treatment because of the scarcity of indium. Based on the analyses of the structure of Indium Tin Oxide (ITO) glass, crushing is demonstrated to be not required. In the present research, a complete non-crushing leaching method was firstly adopted to recycle indium from waste LCDs, and the ultrasonic waves was applied in the leaching process. The results demonstrated that indium can be leached efficiently with even a low concentration of chloride acid (HCl) without extra heating. About 96.80% can be recovered in 60mins, when the ITO glass was leached by 0.8MHCl with an enhancement of 300W ultrasonic waves. The indium leaching process is abridged free from crushing, and proves to be of higher efficiency. In addition, the ultrasonic wave influence on leaching process was also explained combing with micron-scale structure of ITO glass.
近年来,大量的液晶显示器(LCD)已成为电子废物(WEEE)的主要来源之一。尽管安全处理是必要的,但由于铟的稀缺,回收铟也是废 LCD 处理的一个重点。基于对铟锡氧化物(ITO)玻璃结构的分析,证明不需要粉碎。在本研究中,首次采用了一种完整的非粉碎浸出方法,从废液晶显示器中回收铟,并在浸出过程中应用了超声波。结果表明,即使在低浓度的盐酸(HCl)中,也无需额外加热,铟也可以被有效地浸出。当 ITO 玻璃在 300W 超声波增强下用 0.8MHCl 浸出 60min 时,铟的回收率可达 96.80%。铟的浸出过程无需粉碎,效率更高。此外,还结合 ITO 玻璃的微米级结构解释了超声波对浸出过程的影响。