Revealing the Correlation between Molecular Structure and Corrosion Inhibition Characteristics of N-Heterocycles in Terms of Substituent Groups.

Controlling metal corrosion can directly address the waste of metal and the environmental pollution and resource depletion caused by metal recycling, very significant factors for green and sustainable development. The addition of corrosion inhibitors is a relatively cost-effective means of corrosion prevention. Among these, N-heterocycles have been widely used because heteroatoms contain lone pairs of electrons that can be strongly adsorbed onto metals, protecting them in highly corrosive environments at relatively low concentrations. However, due to the large variety of N-heterocycles, their corrosion inhibition characteristics have seldom been compared; therefore, the selection of appropriate N-heterocycles in the development of anti-corrosion products for specific applications was very difficult. This review systematically analyzed the influence of different substituents on the corrosion inhibition performance of N-heterocycles, including different alkyl chain substituents, electron-donating and electron-withdrawing substituents, and halogen atoms, respectively. The correlation between the molecular structure and corrosion inhibition characteristics of N-heterocycles was comprehensively revealed, and their action mechanism was analyzed deeply. In addition, the toxicity and biodegradability of N-heterocycles was briefly discussed. This study has provided a significant guideline for the development of green, promising corrosion inhibitors for advanced manufacturing and clean energy equipment protection.