Evaluation of Cross-Linked Polyamide 6 Micro-Indentation Properties: TAIC Concentration and Electron Radiation Intensity.

Nowadays, technical practice puts emphasis on improving selected material properties of polymers which could lead to new applications. Material properties can be modified in numerous ways, among which is radiation treatment. This study looks into the influence of beta radiation on several properties of polyamide 6, e.g., indentation hardness, modulus and creep. Main changeable parameters were the concentration of triallyl isocyanurate (TAIC), which promotes cross-linking, and intensity of radiation. The concentration was in the range from 2 to 6 wt.%, while the radiation dose was 0, 66, 99 and 132 kGy. The treated materials were measured for indentation hardness, modulus and creep. Degree of cross-linking was verified by thermo-mechanical analysis (TMA), while degradation processes was investigated by Fourier-transform infrared spectroscopy (FTIR). The results indicate that electron radiation positively affects the tested material properties. The best results were seen in polyamide with 6 wt.% of TAIC, which demonstrated a 38% improvement in mechanical properties after exposure to 132 kGy. This improvement in properties affects the final parts and their application (e.g., in the automotive industry-engine parts; in electrical engineering-insulation of wires and cables; and in industry-pipes for underfloor heating, etc.).