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开瓶 Haloanisoles 葡萄酒。

Uncorking Haloanisoles in Wine.

机构信息

Department of Horticultural Sciences, Texas A&M University, College Station, TX 77843, USA.

出版信息

Molecules. 2023 Mar 10;28(6):2532. doi: 10.3390/molecules28062532.

DOI:10.3390/molecules28062532
PMID:36985504
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10054257/
Abstract

Haloanisoles in wine have devastating effects on the aroma and quality of the wine. 2,4,6-trichloroanisole (TCA) was discovered and coined as "cork taint" in 1982. However, we now understand that there are many more haloanisoles that contribute to these musty odors, including 2,4,6-Tribromoanisiole (TBA), 2,3,4,6-tetrachloroanisole (TeCA), and pentachloroanisole (PCA). While TCA, TeCA, and PCA can all be traced back to the cork, TBA's phenol precursor is ubiquitous in building material as a fire retardant, making it a much larger vector. All haloanisoles have the ability to aerosolize and resettle onto surfaces in the winery, making this a very difficult problem to eliminate. This literature review will cover the multiple haloanisoles found in wine, their sensory impacts, their effect on wine quality, and current methodologies with regard to their analysis.

摘要

葡萄酒中的卤苯甲醚类化合物对葡萄酒的香气和质量有破坏性影响。2,4,6-三氯苯甲醚(TCA)于 1982 年被发现并被命名为“软木塞污染”。然而,我们现在知道,还有许多其他卤苯甲醚类化合物会导致这些发霉的气味,包括 2,4,6-三溴苯甲醚(TBA)、2,3,4,6-四氯苯甲醚(TeCA)和五氯苯甲醚(PCA)。虽然 TCA、TeCA 和 PCA 都可以追溯到软木塞,但 TBA 的酚类前体作为阻燃剂在建筑材料中无处不在,使其成为一个更大的载体。所有卤苯甲醚类化合物都有能力气溶胶化并重新沉降在酒厂的表面上,因此这是一个非常难以解决的问题。本文综述了葡萄酒中发现的多种卤苯甲醚类化合物,它们的感官影响,它们对葡萄酒质量的影响,以及目前关于它们分析的方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/435c/10054257/386dfe310d38/molecules-28-02532-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/435c/10054257/386dfe310d38/molecules-28-02532-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/435c/10054257/386dfe310d38/molecules-28-02532-g001.jpg

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本文引用的文献

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Airborne Fumigants and Residual Chemicals in Shipping Containers Arriving in New Zealand.抵达新西兰的航运集装箱中的空气熏蒸剂和残留化学品。
Ann Work Expo Health. 2022 Apr 22;66(4):481-494. doi: 10.1093/annweh/wxab090.
2
Use of alimentary film for selective sorption of haloanisoles from contaminated red wine.利用食用薄膜从污染红葡萄酒中选择吸附卤代苯甲醚。
Food Chem. 2021 Jul 15;350:128364. doi: 10.1016/j.foodchem.2020.128364. Epub 2020 Nov 2.
3
Thermal Desorption-Vocus Enables Online Nondestructive Quantification of 2,4,6-Trichloroanisole in Cork Stoppers below the Perception Threshold.
热脱附-顶空在线法实现了低于感官阈值的软木塞中 2,4,6-三氯苯甲醚的无损定量分析。
Anal Chem. 2020 Jul 21;92(14):9823-9829. doi: 10.1021/acs.analchem.0c01326. Epub 2020 Jun 30.
4
Testing the Sensitivity of Potential Panelists for Wine Taint Compounds Using a Simplified Sensory Strategy.使用简化感官策略测试潜在小组成员对葡萄酒异味化合物的敏感性。
Foods. 2018 Oct 24;7(11):176. doi: 10.3390/foods7110176.
5
"Cork taint" responsible compounds. Determination of haloanisoles and halophenols in cork matrix: A review.“软木塞污染”相关化合物。软木基质中卤代苯甲醚和卤代酚的测定:综述
Talanta. 2017 Dec 1;175:82-92. doi: 10.1016/j.talanta.2017.07.029. Epub 2017 Jul 11.
6
The occurrence of haloanisoles as an emerging odorant in municipal tap water of typical cities in China.卤代苯类作为新兴嗅味物质在我国典型城市自来水的出现。
Water Res. 2016 Jul 1;98:242-9. doi: 10.1016/j.watres.2016.04.023. Epub 2016 Apr 16.
7
Recent developments in the analysis of musty odour compounds in water and wine: A review.水和葡萄酒中霉味化合物分析的最新进展:综述
J Chromatogr A. 2016 Jan 8;1428:72-85. doi: 10.1016/j.chroma.2015.09.008. Epub 2015 Sep 5.
8
A simple and sensitive vortex assisted liquid-liquid microextraction method for the simultaneous determination of haloanisoles and halophenols in wines.一种用于同时测定葡萄酒中卤代苯甲醚和卤代酚的简单灵敏的涡旋辅助液-液微萃取方法。
Talanta. 2014 Oct;128:1-8. doi: 10.1016/j.talanta.2014.04.005. Epub 2014 Apr 13.
9
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