Pei Shuang, Fu Zongying, Gou Jinsheng, Lu Yun
Key Laboratory of Wood Material Science and Application, Beijing Forestry University, Ministry of Education, Beijing 100083, China.
Beijing Key Laboratory of Wood Science and Engineering, Beijing Forestry University, Beijing 100083, China.
Polymers (Basel). 2023 Mar 13;15(6):1417. doi: 10.3390/polym15061417.
Traditional cushioning package materials, such as Expended Polystyrene (EPS) and Expanded Polyethylene (EPE), were made with petroleum-based plastics, which are harmful to the environment. It is crucial to develop renewable bio-based cushioning materials that can replace the aforementioned foams due to the rising energy demands of human society and the depletion of fossil fuels. Herein, we report an effective strategy for creating anisotropic elastic wood with special spring-like lamellar structures. Selective removal of lignin and hemicellulose by simple chemical treatment and thermal treatment of the samples after freeze-drying results in an elastic material with good mechanical properties. The resulting elastic wood has a reversible compression rate of 60% and a high elastic recovery (99% height retention after 100 cycles at 60% strain). Drop tests revealed that the elastic wood has excellent cushioning properties. In addition, the chemical and thermal treatments also enlarge the pores in the material, which is favorable for subsequent functionalization. By loading the elastic wood with a muti-walled carbon nanotube (MWCNT), electromagnetic shielding properties are achieved, while the mechanical properties of elastic wood remain unchanged. Electromagnetic shielding materials can effectively suppress various electromagnetic waves propagating through space and the resulting electromagnetic interference and electromagnetic radiation, improve the electromagnetic compatibility of electronic systems and electronic equipment, and ensure the safety of information.
传统的缓冲包装材料,如发泡聚苯乙烯(EPS)和发泡聚乙烯(EPE),是由石油基塑料制成的,对环境有害。由于人类社会能源需求的不断增长和化石燃料的枯竭,开发能够替代上述泡沫材料的可再生生物基缓冲材料至关重要。在此,我们报道了一种制备具有特殊弹簧状层状结构的各向异性弹性木材的有效策略。通过对冻干后的样品进行简单的化学处理和热处理,选择性去除木质素和半纤维素,得到了一种具有良好力学性能的弹性材料。所得弹性木材的可逆压缩率为60%,具有较高的弹性回复率(在60%应变下经过100次循环后高度保留率为99%)。跌落测试表明,弹性木材具有优异的缓冲性能。此外,化学和热处理还扩大了材料中的孔隙,有利于后续的功能化。通过在弹性木材中负载多壁碳纳米管(MWCNT),实现了电磁屏蔽性能,同时弹性木材的力学性能保持不变。电磁屏蔽材料可以有效抑制各种在空间中传播的电磁波以及由此产生的电磁干扰和电磁辐射,提高电子系统和电子设备的电磁兼容性,并确保信息安全。