Cellulose/Grape-Seed-Extract Composite Films with High Transparency and Ultraviolet Shielding Performance Fabricated from Old Cotton Textiles.

Plastics displaying many merits have been indispensable in daily life and they still maintain the strong momentum of development. Nevertheless, petroleum-based plastics possess a stable polymer structure and most of them are incinerated or accumulated in the environment, leading to devastating impacts on our ecology system. Thus, exploiting renewable and biodegradable materials to substitute or replace these traditional petroleum-derived plastics is an urgent and important task. In this work, renewable and biodegradable all-biomass cellulose/grape-seed-extract (GSEs) composite films with high transparency and anti-ultraviolet performance were fabricated successfully from pretreated old cotton textiles (P-OCTs) using a relatively simple, green, yet cost-effective, approach. It is proved that the obtained cellulose/GSEs composite films exhibit good ultraviolet shielding performance without sacrificing their transparency, and their UV-A and UV-B blocking values can reach as high as nearly 100%, indicating the good UV-blocking performance of GSEs. Meanwhile, the cellulose/GSEs film show higher thermal stability and water vapor transmission rate (WVTR) than most common plastics. Moreover, the mechanical property of the cellulose/GSEs film can be adjusted by the addition of a plasticizer. Briefly, the transparent all-biomass cellulose/grape-seed-extracts composite films with high anti-ultraviolet capacity were manufactured successfully and they can be used as potential materials in the packaging field.