二茂铁驱动的单链聚合物压缩。
Ferrocene-driven single-chain polymer compaction.
作者信息
Gillhuber Sebastian, Holloway Joshua O, Frisch Hendrik, Feist Florian, Weigend Florian, Barner-Kowollik Christopher, Roesky Peter W
机构信息
Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, Karlsruhe 76131, Germany.
School of Chemistry and Physics, Queensland University of Technology (QUT), 2 George Street, Brisbane QLD 4000, Australia.
出版信息
Chem Commun (Camb). 2023 Apr 13;59(31):4672-4675. doi: 10.1039/d3cc00736g.
We introduce single-chain nanoparticles (SCNPs) exclusively folded by covalently bonded ferrocene units. Specifially, we demonstrate the ability of 2-ferrocenyl-1,10-phenanthroline to fuse single-chain collapse with the concomitant introduction of a donor functionality allowing the installation of a Pd-catalytic site, affording the first heterobimetallic ferrocene-functionalized SCNP.
我们引入了由共价键合的二茂铁单元专门折叠而成的单链纳米颗粒（SCNP）。具体而言，我们展示了2-二茂铁基-1,1,0-菲咯啉将单链折叠与同时引入供体功能相结合的能力，该功能允许安装钯催化位点，从而得到首个异双金属二茂铁功能化的SCNP。
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