Xu Zhichao, Wu Di, Fang Cong, Li Yuanzhe
School of Information and Business Management, Dalian Neusoft University of Information, Dalian, China.
School of Design, The Hong Kong Polytechnic University, HongKong SAR, HongKong.
Des Monomers Polym. 2023 Mar 29;26(1):90-105. doi: 10.1080/15685551.2023.2194174. eCollection 2023.
Microporous organic polymers (MOPs) are a new type of porous materials, which have advantages of synthetic diversity, chemical and physical stability, microporous size controllability, etc. MOPs indicate broad applications in various fields such as heterogeneous catalysis, gas adsorption, separation, and storage. In recent years, MOPs have attracted an enormous attention in greenhouse gas capture due to their great potential in physisorptive gas storage. Carbazole and its derivatives have been studied extensively as Metal-Organic Polyhedra (MOPs) building blocks due to their unique structural features and versatile functionalization possibilities. This paper systematically reviews the synthesis, characterization and application of carbazole-based polymers, and relationship of structures and properties of these polymers. The application of the polymers in carbon dioxide (CO) capture field is analysed taking advantage of their adjustable microporous structure and electron rich properties. This review also provides novel insights regarding functional polymer materials that have high ability of greenhouse gas capture and absorbing selectivity will be obtained by reasonable molecular design and efficient synthesis.
微孔有机聚合物（MOPs）是一类新型多孔材料，具有合成多样性、化学和物理稳定性、微孔尺寸可控性等优点。MOPs在多相催化、气体吸附、分离和储存等各个领域都有广泛应用。近年来，由于MOPs在物理吸附气体储存方面具有巨大潜力，它们在温室气体捕获方面引起了极大关注。咔唑及其衍生物因其独特的结构特征和多样的功能化可能性，作为金属有机多面体（MOPs）的构建块得到了广泛研究。本文系统综述了咔唑基聚合物的合成、表征和应用，以及这些聚合物的结构与性能关系。利用其可调的微孔结构和富电子性质，分析了该聚合物在二氧化碳（CO）捕获领域的应用。本综述还提供了新的见解，即通过合理的分子设计和高效合成，有望获得具有高温室气体捕获能力和吸收选择性的功能高分子材料。
