定制共价有机框架中的微孔。
Tailoring microporosity in covalent organic frameworks.
机构信息
Department of Chemistry and Biochemistry University of South Carolina 631 Sumter St., Columbia, SC 29208 (USA).
出版信息
Adv Mater. 2008 Jul 17;20(14):2741-6. doi: 10.1002/adma.200800030. Epub 2008 Jun 5.
PMID:25213899
Abstract
The microporosity of covalent organic frameworks (COFs) is tailored using a facile synthetic approach that introduces alkyl functionalities into the pore and generates networks with pore diameters between 1-2 nm. The added substituents significantly alter the host-guest properties of the resulting materials.
摘要
利用一种简便的合成方法来调整共价有机骨架（COFs）的微孔率，该方法在孔中引入了烷基官能团，并生成了孔径在 1-2nm 之间的网络。引入的取代基会显著改变所得材料的主客体性能。
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