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化学机械平面化过程中摩擦和温度的影响

The Effects of Friction and Temperature in the Chemical-Mechanical Planarization Process.

作者信息

Ilie Filip, Minea Ileana-Liliana, Cotici Constantin Daniel, Hristache Andrei-Florin

机构信息

Department of Machine Elements and Tribology, Polytechnic University of Bucharest, Spl. Independentei 313, 060042 Bucharest, Romania.

Department of Biotechnical Systems, Polytechnic University of Bucharest, Spl. Independentei 313, 060042 Bucharest, Romania.

出版信息

Materials (Basel). 2023 Mar 23;16(7):2550. doi: 10.3390/ma16072550.

Abstract

Chemical-mechanical planarization (CMP) represents the preferred technology in which both chemical and mechanical interactions are combined to achieve global planarization/polishing of wafer surfaces (wafer patterns from metal with a selective layer, in this paper). CMP is a complex process of material removal process by friction, which interferes with numerous mechanical and chemical parameters. Compared with chemical parameters, mechanical parameters have a greater influence on the material removal rate (). The mechanical parameters manifest by friction force () and heat generated by friction in the CMP process. The can be estimated by its monitoring in the CMP process, and process temperature is obtained with help of an infrared rays (IR) sensor. Both the and the increase by introducing colloidal silica (SiO) as an abrasive into the selective layer CMP slurry. The calculated wafer non-uniformity () was correlated with the friction coefficient (). The control of and of the slurry stability is important to maintain a good quality of planarization with optimal results, because participates in mechanical abrasion, and large may generate defects on the wafer surface. Additionally, the temperature generated by the increases as the SiO concentration increases. The of the selective layer into the CMP slurry showed a non-linear (Prestonian) behavior, useful not only to improve the planarization level but to improve its non-uniformity due to the various pressure distributions. The evaluation of the allowed the calculation of the friction energy () to highlight the chemical contribution in selective-layer CMP, from which it derived an empirical model for the material removal amount () and validated by the CMP results. With the addition of abrasive nanoparticles into the CMP slurry, their concentration increased and the of the selective layer improved; and can be increased due to the number of chemisorbed active abrasive nanoparticles by the selective layer. Therefore, a single abrasive was considered to better understand the effect of SiO concentration as an abrasive and of the features depending on abrasive nanoparticle concentration. This paper highlights the correlation between friction and temperature of the SiO slurry with CMP results, useful to examine the temperature distribution. All the depending on after planarization with various SiO concentrations had a non-linear characteristic. The obtained results can help in developing a CMP process more effectively.

摘要

化学机械平面化(CMP)是一种首选技术,它将化学和机械相互作用结合起来,以实现晶圆表面(本文中为带有选择性层的金属晶圆图案)的全局平面化/抛光。CMP是一个通过摩擦进行材料去除的复杂过程,它受到众多机械和化学参数的影响。与化学参数相比,机械参数对材料去除率有更大的影响。机械参数通过摩擦力()和CMP过程中摩擦产生热来体现。摩擦力可通过在CMP过程中的监测来估算,而过程温度借助红外线(IR)传感器获得。通过在选择性层CMP浆料中引入胶体二氧化硅(SiO)作为磨料,摩擦力和热都会增加。计算得到的晶圆不均匀性()与摩擦系数()相关。控制摩擦力和浆料稳定性对于以最佳结果保持良好的平面化质量很重要,因为摩擦力参与机械磨损,而较大的摩擦力可能会在晶圆表面产生缺陷。此外,随着SiO浓度的增加,摩擦力产生的温度也会升高。选择性层进入CMP浆料的过程表现出非线性(普雷斯顿)行为,这不仅有助于提高平面化水平,还能因各种压力分布改善其不均匀性。对摩擦力的评估使得能够计算摩擦能(),以突出选择性层CMP中的化学作用,从中得出了材料去除量()的经验模型,并通过CMP结果进行了验证。随着磨料纳米颗粒添加到CMP浆料中,它们的浓度增加,选择性层的摩擦力得到改善;由于选择性层化学吸附的活性磨料纳米颗粒数量增加,摩擦力和热都可以增加。因此,考虑单一磨料有助于更好地理解作为磨料的SiO浓度的影响以及取决于磨料纳米颗粒浓度的摩擦力特征。本文强调了SiO浆料的摩擦与温度和CMP结果之间的相关性,这有助于研究温度分布。在使用各种SiO浓度进行平面化后,所有取决于摩擦力的参数都具有非线性特征。所得结果有助于更有效地开发CMP工艺。

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