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用于立体光刻3D打印的具有凝胶行为的高稳定性陶瓷浆料的制备

Preparation of High-Stability Ceramic Slurry with Gel Behavior for Stereolithography 3D Printing.

作者信息

Wang Ning, Chang Hai, Zhang Chi, Wu Yingna, Yang Rui, Zhang Xing, Zhai Zirong

机构信息

Center for Adaptive System Engineering, ShanghaiTech University, 393 Huaxia Middle Road, Shanghai 201210, China.

Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China.

出版信息

Materials (Basel). 2023 Apr 1;16(7):2816. doi: 10.3390/ma16072816.

Abstract

Maintaining sufficient uniformity and stability of a ceramic slurry throughout the printing cycle is key to ensuring the performance of ceramic parts in ceramic-slurry stereolithography. In this study, a stable three-dimensional network structure was introduced into a slurry to achieve slurry uniformity and stability based on rheology theory. The effects of the particle size, solid loading, dispersant content, and gelling agent content on the stability of the three-dimensional network structure in the slurry were analyzed. Relatively stable three-dimensional network structures were constructed to achieve 4-week stability of micron- and submicron-size particle slurries by adjusting the contents of the dispersant and gelling agent. Stabilization ideas for different particle size ranges are provided. In addition, an empirical stability model was obtained based on the experimental results. When the predicted empirical stability factor of was less than 0.035, the slurry exhibited good stability.

摘要

在陶瓷浆料立体光刻技术中,在整个打印周期内保持陶瓷浆料足够的均匀性和稳定性是确保陶瓷部件性能的关键。在本研究中,基于流变学理论,将稳定的三维网络结构引入浆料中以实现浆料的均匀性和稳定性。分析了粒径、固体含量、分散剂含量和胶凝剂含量对浆料中三维网络结构稳定性的影响。通过调整分散剂和胶凝剂的含量,构建了相对稳定的三维网络结构,以实现微米级和亚微米级颗粒浆料4周的稳定性。提供了不同粒径范围的稳定化思路。此外,根据实验结果获得了一个经验稳定性模型。当预测的经验稳定性因子小于0.035时,浆料表现出良好的稳定性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f522/10095992/fd0a208ee953/materials-16-02816-g001.jpg

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