Li Jian, Liu Zuming, Zhou Huan, Ye Shupeng, Zhang Yazhou, Liu Tao, Jiang Daoyan, Chen Lei, Zhou Runxing
State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083, China.
Materials (Basel). 2023 Apr 6;16(7):2912. doi: 10.3390/ma16072912.
The fabrication of high-performance copper alloys by selective laser melting (SLM) is challenging, and establishing relationships between the process parameters and microstructures is necessary. In this study, Cu-Cr-Nb-Ti alloy is manufactured by SLM, and the microstructures of the alloy are investigated by X-ray diffraction (XRD), scanning electron microscope (SEM), and electron backscatter diffraction (EBSD). The effects of processing parameters such as laser power and scanning speed on the relative density, defects, microstructures, mechanical properties, and electrical conductivity of the Cu-Cr-Nb-Ti alloy are studied. The optimal processing window for fabricating Cu-Cr-Nb-Ti alloy by SLM is determined. Face-centered cubic (FCC) Cu diffraction peaks shifting to small angles are observed, and there are no diffraction peaks related to the second phase. The grains of XY planes have a bimodal distribution with an average grain size of 24-55 μm. Fine second phases with sizes of less than 50 nm are obtained. The microhardness, tensile strength, and elongation of the Cu-Cr-Nb-Ti alloy manufactured using the optimum processing parameters, laser power of 325 W and scanning speed of 800 mm/s, are 139 HV0.2, 416 MPa, and 27.8%, respectively, and the electrical conductivity is 15.6% IACS (International Annealed Copper Standard). This study provides a feasible scheme for preparing copper alloys with excellent performance and complex geometries.
通过选择性激光熔化(SLM)制备高性能铜合金具有挑战性,因此建立工艺参数与微观结构之间的关系很有必要。在本研究中,采用SLM制造了Cu-Cr-Nb-Ti合金,并通过X射线衍射(XRD)、扫描电子显微镜(SEM)和电子背散射衍射(EBSD)对该合金的微观结构进行了研究。研究了激光功率和扫描速度等工艺参数对Cu-Cr-Nb-Ti合金的相对密度、缺陷、微观结构、力学性能和电导率的影响。确定了通过SLM制备Cu-Cr-Nb-Ti合金的最佳工艺窗口。观察到面心立方(FCC)铜衍射峰向小角度移动,且没有与第二相相关的衍射峰。XY平面的晶粒具有双峰分布,平均晶粒尺寸为24-55μm。获得了尺寸小于50nm的细小第二相。使用最佳工艺参数(激光功率325W,扫描速度800mm/s)制造的Cu-Cr-Nb-Ti合金的显微硬度、抗拉强度和伸长率分别为139HV0.2、416MPa和27.8%,电导率为15.6%IACS(国际退火铜标准)。本研究为制备具有优异性能和复杂几何形状的铜合金提供了一种可行的方案。