College of Chemistry, Zhengzhou University, 450001 Zhengzhou, China.
Center of Air Quality Simulation and System Analysis, Chinese Academy of Environmental Planning, 100043 Beijing, China.
Sci Total Environ. 2023 Jul 15;882:163436. doi: 10.1016/j.scitotenv.2023.163436. Epub 2023 Apr 12.
To evaluate the effects of the various ozone (O) control approaches on environmental health and health inequalities, 121 reduction scenarios for nitrogen oxides (NO) and volatile organic compounds (VOCs) were developed, and their environmental health impacts were calculated. With the target of achieving the 90th percentile of the daily maximum 8 h mean O concentration (MDA8-90th) of 160 μg/m in Beijing-Tianjin-Hebei and its surroundings ("2 + 26" cities), three typical scenarios namely, High-NO reduction ratio (HN, NO/VOCs = 6:1), High-VOCs reduction ratio (HV, NO/VOCs = 3:7), and Balanced reduction ratio (Balanced, NO/VOCs = 1:1) were investigated. The results show that O formation is currently NO-limited at the regional scale, while some developed cities are VOC-limited, indicating that NO mitigation should be the core for achieving the targeted concentration (160 μg/m) at the regional scale, whereas cities such as Beijing in the short term should focus on VOCs mitigation. The population-weighted O concentrations in the HN, Balanced, and HV scenarios were 159.19, 159.19, and 158.44 μg/m, respectively. In addition, the O-related premature mortality was 41,320 in "2 + 26" cities; control measures under HN, Balanced, and HV could potentially decrease O-related premature deaths by 59.94 %, 60.25 %, and 71.48 %, respectively. The HV scenario has been found to be more advantageous in lowering the O-related environmental health impacts than the HN and Balanced scenarios. It was further found that premature deaths avoided by the HN scenario were mainly concentrated in economically unadvanced regions, whereas those prevented by the HV scenario were mainly concentrated in developed cities. This may lead to geographical inequities in environmental health. As ozone pollution in large cities with high population density is primarily VOC-limited, decrease in VOCs should be focused on in the short term to avoid more O-related premature deaths, whereas NO control may be more important in decreasing ozone concentrations and ozone-related mortality in the future.
为了评估各种臭氧(O)控制方法对环境健康和健康不平等的影响,开发了 121 种氮氧化物(NO)和挥发性有机化合物(VOCs)减排方案,并计算了它们对环境健康的影响。以实现京津冀及其周边地区(“2+26”城市)日最大 8 小时平均 O 浓度(MDA8-90th)第 90 百分位数 160μg/m3 的目标为目标,研究了三种典型方案,即高氮氧化物减排比(HN,NO/VOCs=6:1)、高挥发性有机化合物减排比(HV,NO/VOCs=3:7)和平衡减排比(Balanced,NO/VOCs=1:1)。结果表明,目前在区域尺度上 O 的形成受 NO 限制,而一些发达城市受 VOC 限制,这表明在区域尺度上实现目标浓度(160μg/m3)应以减少 NO 为核心,而短期内北京等城市应重点减少 VOC。在 HN、平衡和 HV 方案中,人口加权 O 浓度分别为 159.19、159.19 和 158.44μg/m3。此外,“2+26”城市的 O 相关过早死亡率为 41320 人;在 HN、平衡和 HV 控制措施下,O 相关过早死亡人数可能分别减少 59.94%、60.25%和 71.48%。结果表明,HV 方案在降低 O 相关环境健康影响方面比 HN 和平衡方案更具优势。进一步发现,HN 方案避免的过早死亡主要集中在经济欠发达地区,而 HV 方案避免的过早死亡主要集中在发达城市。这可能导致环境健康的地理不平等。由于人口密度大的大城市臭氧污染主要受 VOC 限制,短期内应重点减少 VOC,以避免更多的 O 相关过早死亡,而未来减少臭氧浓度和臭氧相关死亡率可能更为重要。