2-脱氧-4-O-膦酰基-3-O-十四烷酰基-2-[(3R)-和(3S)-3-十四烷酰氧基十四烷酰胺基]-D-葡萄糖的合成：一对与细菌脂多糖A相关的4-O-膦酰基-D-葡糖胺衍生物（GLA-27）的非对映异构体。
Synthesis of 2-deoxy-4-O-phosphono-3-O-tetradecanoyl-2-[(3R)- and (3S)-3-tetradecanoyloxytetradecanamido]-D-glucose: a diastereoisomeric pair of 4-O-phosphono-D-glucosamine derivatives (GLA-27) related to bacterial lipid A.
作者信息
Kiso M, Tanaka S, Tanahashi M, Fujishima Y, Ogawa Y, Hasegawa A
出版信息
Carbohydr Res. 1986 May 1;148(2):221-34. doi: 10.1016/s0008-6215(00)90390-2.
PMID:3708630
Abstract
The diastereoisomeric, 4-O-phosphono-D-glucosamine derivatives named in the title have been synthesized, starting from benzyl 2-amino-2-deoxy-4,6-O-isopropylidene-beta-D-glucopyranoside and (3RS)-3-hydroxytetradecanoic acid.
摘要
已从苄基 2-氨基-2-脱氧-4,6-O-亚异丙基-β-D-吡喃葡萄糖苷和(3RS)-3-羟基十四烷酸出发，合成了标题中命名的非对映异构的 4-O-膦酰基-D-葡糖胺衍生物。
Zotero 插件