Wu Huihai, Liu Xiaochuan, Zhu Keyong, Huang Yong
School of Aeronautic Science and Engineering, Beihang University, Beijing 100191, China.
Nanomaterials (Basel). 2023 Apr 20;13(8):1425. doi: 10.3390/nano13081425.
Two-dimensional (2D) materials and their vertically stacked heterostructures have attracted much attention due to their novel optical properties and strong light-matter interactions in the infrared. Here, we present a theoretical study of the near-field thermal radiation of 2D vdW heterostructures vertically stacked of graphene and monolayer polar material (2D hBN as an example). An asymmetric Fano line shape is observed in its near-field thermal radiation spectrum, which is attributed to the interference between the narrowband discrete state (the phonon polaritons in 2D hBN) and a broadband continuum state (the plasmons in graphene), as verified by the coupled oscillator model. In addition, we show that 2D van der Waals heterostructures can achieve nearly the same high radiative heat flux as graphene but with markedly different spectral distributions, especially at high chemical potentials. By tuning the chemical potential of graphene, we can actively control the radiative heat flux of 2D van der Waals heterostructures and manipulate the radiative spectrum, such as the transition from Fano resonance to electromagnetic-induced transparency (EIT). Our results reveal the rich physics and demonstrate the potential of 2D vdW heterostructures for applications in nanoscale thermal management and energy conversion.
二维(2D)材料及其垂直堆叠的异质结构因其新颖的光学性质以及在红外波段强烈的光与物质相互作用而备受关注。在此,我们对由石墨烯和单层极性材料(以二维六方氮化硼为例)垂直堆叠而成的二维范德华异质结构的近场热辐射进行了理论研究。在其近场热辐射光谱中观察到一种不对称的法诺线形,这归因于窄带离散态(二维六方氮化硼中的声子极化激元)与宽带连续态(石墨烯中的等离激元)之间的干涉,这一结论通过耦合振子模型得到了验证。此外,我们表明二维范德华异质结构能够实现与石墨烯几乎相同的高辐射热流,但具有明显不同的光谱分布,尤其是在高化学势情况下。通过调节石墨烯的化学势,我们可以主动控制二维范德华异质结构的辐射热流并操控辐射光谱,例如从法诺共振到电磁诱导透明(EIT)的转变。我们的结果揭示了丰富的物理特性,并展示了二维范德华异质结构在纳米尺度热管理和能量转换应用中的潜力。