Ba Huaiqiang, Guo Luxin, Huan Haiyang, Zhang Shibo, Lin Zhiwei
CRCC Yunnan Investment Co., Ltd., Kunming 650299, China.
Faculty of Civil Engineering and Mechanics, Kunming University of Science and Technology, Kunming 650500, China.
Polymers (Basel). 2023 Apr 19;15(8):1946. doi: 10.3390/polym15081946.
Epoxy resin adhesive for pavement is often insufficient in flexibility and toughness. Therefore, a new type of toughening agent was prepared to overcome this shortcoming. To achieve the best toughening effect of a self-made toughening agent on an epoxy resin adhesive, its ratio to the epoxy resin needs to be optimally selected. A curing agent, a toughening agent, and an accelerator dosage were chosen as independent variables. The epoxy resin's adhesive tensile strength, elongation at break, flexural strength, and flexural deflection were used as response values to establish a single-objective prediction model of epoxy resin mechanical property indexes. Response surface methodology (RSM) was used to determine the single-objective optimal ratio and analyze the effect of factor interaction on epoxy resin adhesive's performance indexes. Based on principal component analysis (PCA), multi-objective optimization was performed using gray relational analysis (GRA) to construct a second-order regression prediction model between the ratio and gray relational grade (GRG) to determine the optimal ratio and to validate it. The results showed that the multi-objective optimization using response surface methodology and gray relational analysis (RSM-GRA) was more effective than the single-objective optimization model. The optimal ratio of epoxy resin adhesive was 100 parts of epoxy resin, 160.7 parts curing agent, 16.1 parts toughening agent, and 3.0 parts accelerator. The measured tensile strength was 10.75 MPa, elongation at break was 23.54%, the bending strength was 6.16 MPa, and the bending deflection was 7.15 mm. RSM-GRA has excellent accuracy for epoxy resin adhesive ratio optimization and can provide a reference for the epoxy resin system ratio optimization design of complex components.
用于路面的环氧树脂胶粘剂通常在柔韧性和韧性方面不足。因此,制备了一种新型增韧剂以克服这一缺点。为了使自制增韧剂对环氧树脂胶粘剂达到最佳增韧效果,需要对其与环氧树脂的比例进行优化选择。选择固化剂、增韧剂和促进剂用量作为自变量。将环氧树脂胶粘剂的拉伸强度、断裂伸长率、弯曲强度和弯曲挠度用作响应值,建立环氧树脂力学性能指标的单目标预测模型。采用响应面法(RSM)确定单目标最佳比例,并分析因素交互作用对环氧树脂胶粘剂性能指标的影响。基于主成分分析(PCA),利用灰色关联分析(GRA)进行多目标优化,构建比例与灰色关联度(GRG)之间的二阶回归预测模型,以确定最佳比例并进行验证。结果表明,采用响应面法和灰色关联分析(RSM-GRA)的多目标优化比单目标优化模型更有效。环氧树脂胶粘剂的最佳比例为环氧树脂100份、固化剂160.7份、增韧剂16.1份和促进剂3.0份。测得的拉伸强度为10.75MPa,断裂伸长率为23.54%,弯曲强度为6.16MPa,弯曲挠度为7.15mm。RSM-GRA在环氧树脂胶粘剂比例优化方面具有优异的准确性,可为复杂部件的环氧树脂体系比例优化设计提供参考。