Bruker Optics GmbH & Co. KG, Rudolf-Plank-Str. 27, 76275 Ettlingen, Germany.
Department of the Built Environment, Aalborg University, Thomas Manns Vej 23, 9220 Aalborg, Denmark.
Anal Methods. 2023 May 11;15(18):2226-2233. doi: 10.1039/d3ay00514c.
In this work, a random decision forest model is built for fast identification of Fourier-transform infrared spectra of the eleven most common types of microplastics in the environment. The random decision forest input data is reduced to a combination of highly discriminative single wavenumbers selected using a machine learning classifier. This dimension reduction allows input from systems with individual wavenumber measurements, and decreases prediction time. The training and testing spectra are extracted from Fourier-transform infrared hyperspectral images of pure-type microplastic samples, automatizing the process with reference spectra and a fast background correction and identification algorithm. Random decision forest classification results are validated using procedurally generated ground truth. The classification accuracy achieved on said ground truths are not expected to carry over to environmental samples as those usually contain a broader variety of materials.
在这项工作中,建立了一个随机决策森林模型,用于快速识别环境中最常见的 11 种微塑料的傅里叶变换红外光谱。随机决策森林输入数据减少到使用机器学习分类器选择的高度有区别的单波数的组合。这种降维允许具有单个波数测量的系统输入,并减少预测时间。训练和测试光谱从纯型微塑料样品的傅里叶变换红外高光谱图像中提取,使用参考光谱和快速背景校正和识别算法实现自动化。随机决策森林分类结果使用程序生成的地面实况进行验证。在上述地面实况上获得的分类准确性预计不会扩展到环境样本,因为这些样本通常包含更广泛的材料种类。