Kılıçarslan Fatma Aytan
Department of Chemistry, Yildiz Technical University, Esenler, 34210, Istanbul, Turkey.
J Fluoresc. 2023 Nov;33(6):2461-2467. doi: 10.1007/s10895-023-03241-z. Epub 2023 May 2.
The synthesis, characterization, spectral, fluorescence properties of bis(4-fluorophenyl)-methoxy substituted nickel phthalocyanine were reported for the first time. The new compound has been characterized by elemental analysis, UV-Vis, FT-IR, H-NMR and mass spectra. The aggregation behaviour of this compound was investigated in the different solvent and concentrations of in CHCl. Phthalocyanine complex did not show any aggregations. The fluorescent properties of the compound in five different solvents such as CHCl CHCl THF, DMF, DMSO were explained. Phthalocyanine complex gave the highest fluorescence quantum yield in CHCl and the lowest fluorescence quantum yield in DMSO.
首次报道了双（4-氟苯基）-甲氧基取代镍酞菁的合成、表征、光谱及荧光性质。该新化合物已通过元素分析、紫外可见光谱、傅里叶变换红外光谱、氢核磁共振光谱和质谱进行了表征。研究了该化合物在不同溶剂及不同浓度氯仿中的聚集行为。酞菁配合物未表现出任何聚集现象。解释了该化合物在氯仿、二氯甲烷、四氢呋喃、二甲基甲酰胺、二甲基亚砜这五种不同溶剂中的荧光性质。酞菁配合物在氯仿中荧光量子产率最高，在二甲基亚砜中荧光量子产率最低。
