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目标厚度和激光辐照度对玻璃中背反射增强激光诱导击穿光谱信号的影响。

Effect of target thickness and laser irradiance on the back-reflection-enhanced laser-induced breakdown spectroscopy signal in glass.

机构信息

Higher Technological Institute (HTI), 10th of Ramadan City, 6th of October Branch, Giza, Egypt.

National Institute of Laser Enhanced Sciences (NILES), Cairo University, Giza, Egypt.

出版信息

Sci Rep. 2023 May 3;13(1):7218. doi: 10.1038/s41598-023-34227-3.

DOI:10.1038/s41598-023-34227-3
PMID:37137952
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10156670/
Abstract

In the work that is being presented here, the effect of sample thickness and laser irradiance on the reduction of the signal-to-background ratio SBG and the plasma parameters, specifically electron temperature and electron density, is being investigated using back-reflection-enhanced laser-induced breakdown spectroscopy (BRELIBS). Copper and silver discs that had been highly polished were attached to the back surface of the glass target, and the Nd-YAG laser beam that was focused on the front surface of the target was tuned to its fundamental wavelength. The thicknesses of the transparent glass samples that were analysed were 1 mm, 3 mm, and 6 mm. One is able to achieve a range of different laser irradiance levels by adjusting the working distance that exists between the target sample and the focusing lens. The end result of this is that the signal-to-background ratio in the BRELIBS spectra of thicker glass samples is significantly lower as compared to the ratio in the spectra of thinner glass samples. In addition, a significant influence of modifying the laser irradiance (by increasing the working distance on the SBG ratio) is seen at various glass thicknesses for both BRELIBS and LIBS, with BRELIBS having a better SBG. Nevertheless, the laser-induced plasma parameter known as the electron temperature has not been significantly impacted by the decrease in the glass thickness.

摘要

在本次呈现的工作中,使用背反射增强激光诱导击穿光谱(BRELIBS)研究了样品厚度和激光辐照度对信号背景比(SBG)和等离子体参数(特别是电子温度和电子密度)降低的影响。将高度抛光的铜和银圆盘附着在玻璃靶材的背面,将聚焦在靶材正面的 Nd-YAG 激光调谐到其基频。分析用透明玻璃样品的厚度分别为 1mm、3mm 和 6mm。通过调节靶样品和聚焦透镜之间的工作距离,可以实现不同的激光辐照度水平。结果是,与较薄玻璃样品的光谱相比,较厚玻璃样品的 BRELIBS 光谱中的信号背景比明显降低。此外,在不同玻璃厚度下,通过增加工作距离(即改变激光辐照度)对 BRELIBS 和 LIBS 的 SBG 比均有显著影响,而 BRELIBS 的 SBG 更好。然而,玻璃厚度降低对激光诱导等离子体参数(即电子温度)没有明显影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/c43cf3a94df1/41598_2023_34227_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/56be0af13969/41598_2023_34227_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/1ae5b59d353b/41598_2023_34227_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/cc7730206c2d/41598_2023_34227_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/e3cc0c7b6446/41598_2023_34227_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/af0ccf12806b/41598_2023_34227_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/a25f820485eb/41598_2023_34227_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/217bd262b357/41598_2023_34227_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/c43cf3a94df1/41598_2023_34227_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/56be0af13969/41598_2023_34227_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/1ae5b59d353b/41598_2023_34227_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/cc7730206c2d/41598_2023_34227_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/e3cc0c7b6446/41598_2023_34227_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/af0ccf12806b/41598_2023_34227_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/a25f820485eb/41598_2023_34227_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/217bd262b357/41598_2023_34227_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3598/10156670/c43cf3a94df1/41598_2023_34227_Fig8_HTML.jpg

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本文引用的文献

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Foods. 2022 Jul 11;11(14):2051. doi: 10.3390/foods11142051.
2
Back-reflection-enhanced laser-induced breakdown spectroscopy (BRELIBS) on transparent materials: Application on archaeological glass.透明材料上的背反射增强激光诱导击穿光谱技术(BRELIBS):在考古玻璃中的应用。
Anal Chim Acta. 2021 Nov 1;1184:339024. doi: 10.1016/j.aca.2021.339024. Epub 2021 Sep 4.
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基于激光诱导击穿光谱法的水中重金属在线定量分析
Opt Express. 2019 Apr 15;27(8):A495-A506. doi: 10.1364/OE.27.00A495.
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Characterization of automobile float glass with laser-induced breakdown spectroscopy and laser ablation inductively coupled plasma mass spectrometry.利用激光诱导击穿光谱和激光烧蚀电感耦合等离子体质谱对汽车浮法玻璃进行表征
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