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基于厌氧氨氧化-羟基磷灰石(HAP)工艺实现消化液中氮磷的同步深度去除和回收:聚焦解决方案视角。

Towards advanced simultaneous nitrogen removal and phosphorus recovery from digestion effluent based on anammox-hydroxyapatite (HAP) process: Focusing on a solution perspective.

机构信息

School of Environmental and Chemical Engineering, Shanghai University, 333 Nanchen Road, Shanghai 200444, China.

Department of Civil and Environmental Engineering, Graduate School of Engineering, Tohoku University, 6-6-06 Aoba, Aramaki-Aza, Sendai, Miyagi 980-8579, Japan.

出版信息

Bioresour Technol. 2023 Aug;381:129117. doi: 10.1016/j.biortech.2023.129117. Epub 2023 May 2.

Abstract

In this paper, the state-of-the-art information on the anammox-HAP process is summarized. The mechanism of this process is systematically expounded, the enhancement of anammox retention by HAP precipitation and the upgrade of phosphorus recovery by anammox process are clarified. However, this process still faces several challenges, especially how to deal with the ∼ 11% nitrogen residues and to purify the recovered HAP. For the first time, an anaerobic fermentation (AF) combined with partial denitrification (PD) and anammox-HAP (AF-PD-Anammox-HAP) process is proposed to overcome the challenges. By AF of the organic impurities of the anammox-HAP granular sludge, organic acid is produced to be used as carbon source for PD to remove the nitrogen residues. Simultaneously, pH of the solution drops, which promotes the dissolution of some inorganic purities such as CaCO. In this way, not only the inorganic impurities are removed, but the inorganic carbon is supplied for anammox bacteria.

摘要

本文总结了厌氧氨氧化-羟基磷灰石(anammox-HAP)工艺的最新研究进展。系统阐述了该工艺的作用机制,阐明了羟基磷灰石沉淀对厌氧氨氧化菌的固定化作用以及该工艺对磷回收的强化作用。然而,该工艺仍面临一些挑战,特别是如何处理约 11%的氮残留和净化回收的羟基磷灰石。本文首次提出了一种厌氧发酵(anaerobic fermentation,AF)联合部分反硝化(partial denitrification,PD)和厌氧氨氧化-羟基磷灰石(anammox-HAP)工艺(AF-PD-Anammox-HAP)来克服这些挑战。通过厌氧氨氧化颗粒污泥中有机杂质的厌氧发酵,产生有机酸作为 PD 的碳源以去除氮残留。同时,溶液的 pH 值下降,促进了 CaCO3 等一些无机杂质的溶解。这样不仅去除了无机杂质,还为厌氧氨氧化菌提供了无机碳源。

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