Opt Express. 2023 Mar 13;31(6):10554-10569. doi: 10.1364/OE.461126.
Here, the influence of dimensional parameters of the trench metal grating on the absorption efficiency of organic solar cells (OSCs) was evaluated. The plasmonic modes were calculated. Due to the capacitance-like charge distribution in a plasmonic configuration, the platform width of grating has a significant influence on the intensity of wedge plasmon polaritons (WPPs) and Gap surface plasmon (GSPs). Stopped-trench gratings would lead to better absorption efficiency than thorough-trenched gratings. The stopped-trench gratings (STG) model with a coating layer showed 77.01% integrated absorption efficiency, which is 19.6% better than previously reported works with 19% less photoactive materials. This model offered 18% integrated absorption efficiency, better than an equivalent planar structure without a coating layer. Specifying the areas with maximum generation on the structure helps us to manage and reduce the thickness and volume of the active layer to control the recombination losses and the cost. We rounded the edges and corners with a curvature radius of 30 nm to investigate tolerance during fabrication. Results demonstrated that the integrated absorption efficiency profile of the blunt model is slightly different from the integrated absorption efficiency profile of the sharp model. Finally, we have studied the wave impedance (Zx) inside the structure. Between the spectrum of λ =∼700 nm to λ=900 nm, an extremely high wave impedance layer was formed. It creates an impedance mismatch between layers and helps us to better trap the incident light ray. STG with a coating layer (STGC) is a promising way to produce OCSs with extremely thin active layers.
在这里,评估了沟槽金属光栅的维度参数对有机太阳能电池(OSC)吸收效率的影响。计算了等离子体模式。由于等离子体结构中的电容式电荷分布,光栅的平台宽度对楔形等离子体激元(WPP)和间隙表面等离子体(GSP)的强度有显著影响。停止沟槽光栅比彻底沟槽光栅具有更好的吸收效率。具有涂层的停止沟槽光栅(STG)模型显示出 77.01%的集成吸收效率,比以前报道的工作提高了 19.6%,同时使用的光活性材料减少了 19%。该模型的集成吸收效率为 18%,优于无涂层等效平面结构。指定结构上最大发电区域有助于我们管理和减少活性层的厚度和体积,以控制复合损耗和成本。我们将边缘和角落倒圆为 30nm 的曲率半径,以研究制造过程中的公差。结果表明,钝模型的积分吸收效率曲线与锐模型的积分吸收效率曲线略有不同。最后,我们研究了结构内部的波阻抗(Zx)。在λ=∼700nm 到λ=900nm 的光谱范围内,形成了一层极高的波阻抗层。它在层之间形成阻抗失配,有助于更好地捕获入射光线。具有涂层的 STG(STGC)是生产具有极薄活性层的 OSC 的一种很有前途的方法。