在无热、无金属和无酸条件下，使用正丁基亚硝酸酯（TBN）作为实用的碳源，简便地制备 - 丁基酰胺。

Facile preparation of -butyl amides under heat-, metal- and acid-free conditions by using -butyl nitrite (TBN) as a practical carbon source.

机构信息

Department of Chemistry, College of Sciences, Koç University, Sariyer, Istanbul 34450, Turkey.

Department of Chemistry & CAS, Panjab University, Chandigarh-160014, India.

出版信息

Chem Commun (Camb). 2023 May 25;59(43):6548-6551. doi: 10.1039/d3cc01168b.

DOI:10.1039/d3cc01168b

PMID:37161946

Abstract

-Butyl nitrite (TBN) is a nontoxic substance that has frequently been used as a source of nitrogen, oxygen, or nitric oxide (NO), but not as a carbon source in chemical transformations. Here, for the first time to the best of our knowledge, we introduced TBN as a source of carbon (-butyl group) for the synthesis of highly valuable -butyl amides from nitriles and water under very mild conditions.

摘要