Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Av. Països Catalans 16, 43007, Tarragona, Spain.
Catalan Institution for Research and Advanced Studies (ICREA), Passeig Lluïs Companys 23, 08010, Barcelona, Spain.
Angew Chem Int Ed Engl. 2023 Jul 10;62(28):e202304084. doi: 10.1002/anie.202304084. Epub 2023 May 31.
Herein, we describe a catalytic intramolecular decarboxylative/desulfonylative sp allylation triggered by sulfinate salts under light irradiation. The reaction is likely enabled by a non-classical, radical-polar crossover mechanism, allowing rapid and reliable access to valuable allyl architectures from readily accessible precursors. The protocol is characterized by its operational simplicity and scalability, employing abundant, commercially available catalysts.
在这里，我们描述了一种在光照下由亚磺酸盐引发的催化分子内脱羧/脱硫芳基烯丙基化反应。该反应可能是通过非经典的自由基-极性交叉机制实现的，从而能够从易得的前体快速、可靠地获得有价值的烯丙基结构。该方法具有操作简单、可规模化的特点，使用丰富、商业可得的催化剂。
Zotero 插件