Li Shuaijun, Chen Deyong, Jia Zhirong, Li Yilin, Li Peiqing, Yu Bin
School of Civil Engineering and Geomatics, Shandong University of Technology, Zibo 255000, China.
School of Transportation and Vehicle Engineering, Shandong University of Technology, Zibo 255000, China.
Materials (Basel). 2023 Apr 25;16(9):3355. doi: 10.3390/ma16093355.
High mud content in the sand has a negative impact on cement mortar but there is little research on Alkali-activated slag (AAS) mortar. In order to explore the impacts of mud content in the sand on the performance of AAS mortar, this paper used sand that contains silt, clay, and a mixture of silt and clay; tested the setting time of AAS with different mud contents of 0%, 2%, 4%, 6%, 8%, and 10%; and measured the unconfined compressive strength and beam flexural strength of 3 d, 7 d, and 28 d AAS mortar specimens. The microstructure of AAS mortar with different kinds of mud was observed by scanning electron microscope (SEM), the elemental composition of the hydration product was tested by energy dispersive spectroscopy (EDS), and the AAS interaction mechanism with different kinds of mud was analyzed. The main conclusions are: the higher the mud content in the sand, the shorter the initial setting time and the longer the final setting time of AAS, mainly because the mud in the sand affects the hydration process; mud content above 4% causes a rapid decrease in the compressive and flexural strengths of AAS mortar, mainly because the mud affects the hydration process and hinders the bonding of the hydration product with the sand. When there is no mud in the sand, the main hydration product of AAS is dense calcium-alumina-silicate-hydrate (C-A-S-H) gel. When the sand contains silt, the hydration product of AAS is loose C-A-S-H gel. When the sand contains clay, the hydration products of AAS contain C-A-S-H gel and a small amount of sodium-aluminum-silicate-hydrate (N-A-S-H), and needle-like crystals. Loose gel and crystals have a negative effect on the AAS mortar strength.
砂中泥含量过高会对水泥砂浆产生负面影响,但关于碱激发矿渣(AAS)砂浆的相关研究较少。为探究砂中泥含量对AAS砂浆性能的影响,本文采用了含粉土、黏土以及粉土与黏土混合物的砂;测试了泥含量分别为0%、2%、4%、6%、8%和10%的AAS的凝结时间;并测定了3d、7d和28d龄期AAS砂浆试件的无侧限抗压强度和梁抗折强度。通过扫描电子显微镜(SEM)观察了不同种类泥的AAS砂浆微观结构,利用能谱仪(EDS)测试了水化产物的元素组成,并分析了AAS与不同种类泥的相互作用机理。主要结论如下:砂中泥含量越高,AAS的初凝时间越短,终凝时间越长,主要是因为砂中的泥影响了水化过程;泥含量超过4%会导致AAS砂浆的抗压强度和抗折强度迅速下降,主要是因为泥影响了水化过程并阻碍了水化产物与砂的粘结。当砂中不含泥时,AAS的主要水化产物是致密的钙铝硅酸盐水合物(C-A-S-H)凝胶。当砂中含有粉土时,AAS的水化产物是疏松的C-A-S-H凝胶。当砂中含有黏土时,AAS的水化产物包含C-A-S-H凝胶和少量的钠铝硅酸盐水合物(N-A-S-H)以及针状晶体。疏松的凝胶和晶体对AAS砂浆强度有负面影响。