Functional Nanosystems, Istituto Italiano di Tecnologia, Via Morego 30, Genova, 16163, Italy.
Nanoelectronic Devices Laboratory, École Polytechnique Fédérale de Lausanne (EPFL), Lausanne, 1015, Switzerland.
Chem Commun (Camb). 2023 Jun 20;59(50):7717-7730. doi: 10.1039/d3cc01125a.
Nowadays, as a result of the emergence of low-dimensional hybrid structures, the scientific community is interested in their interfacial carrier dynamics, including charge transfer and energy transfer. By combining the potential of transition metal dichalcogenides (TMDs) and nanocrystals (NCs) with low-dimensional extension, hybrid structures of semiconducting nanoscale matter can lead to fascinating new technological scenarios. Their characteristics make them intriguing candidates for electronic and optoelectronic devices, like transistors or photodetectors, bringing with them challenges but also opportunities. Here, we will review recent research on the combined TMD/NC hybrid system with an emphasis on two major interaction mechanisms: energy transfer and charge transfer. With a focus on the quantum well nature in these hybrid semiconductors, we will briefly highlight state-of-the-art protocols for their structure formation and discuss the interaction mechanisms of energy charge transfer, before concluding with a perspective section that highlights novel types of interactions between NCs and TMDs.
如今,由于低维杂化结构的出现,科学界对它们的界面载流子动力学(包括电荷转移和能量转移)产生了兴趣。通过将过渡金属二卤化物(TMDs)和纳米晶体(NCs)与低维延伸相结合,半导体纳米物质的杂化结构可以带来引人注目的新技术前景。它们的特性使它们成为电子和光电子器件(如晶体管或光电探测器)的有趣候选者,带来了挑战,但也带来了机遇。在这里,我们将回顾最近关于 TMD/NC 杂化系统的研究,重点介绍两种主要的相互作用机制:能量转移和电荷转移。我们将重点关注这些杂化半导体中的量子阱性质,简要介绍其结构形成的最新协议,并讨论能量-电荷转移的相互作用机制,最后以一个强调 NCs 和 TMDs 之间新型相互作用的视角部分结束。