Rebecchi Luca, Martin Irene, Albo Ivet Maqueira, Ranjan Priyadarshi, Gatti Teresa, Scotognella Francesco, Rubino Andrea, Kriegel Ilka
Functional Nanosystems, Istituto Italiano di Tecnologia, via Morego 30, 16163, Genova, Italy.
Dipartimento di Chimica e Chimica Industriale, Università degli Studi di Genova, Via Dodecaneso 31, 16146, Genova, Italy.
Chemistry. 2025 Feb 6;31(8):e202401711. doi: 10.1002/chem.202401711. Epub 2024 Dec 11.
This work describes the scalability process of a continuous-injection protocol employed to produce tin-doped indium oxide nanocrystal dispersions. Different levels of manipulation starting from the synthesis and processing also related to the tuning of the optical response (considering the peculiar combination of UV and NIR absorption with visible transparency) make these materials incredibly versatile. But one of the most attractive features concern the modulation of their charge carrier density through chemical or post-synthetic doping, as for the case of core-shell materials, expanding the properties of the core composition. In addition, the colloidal nature of such materials allows for easy solution processing which enables an extensive use in different applications within current thin films base technologies. It is therefore important to push forward the lab-scale synthesis to properly address the commercial fabrication requirements without any loss in quality. Uniformity is crucial for industrial applications, ensuring predictable performance and facilitating the integration of these nanoparticles into optoelectronic devices. The method here developed allowed a transition from mg-scale to gram-scale product mass outputs, while retaining stability in terms of particle size distribution, morphology, crystallinity, and optical properties. This research establishes a robust framework for the scalable production of metal oxide nanoparticles with consistent properties, enhancing their viability for widespread use in optoelectronic applications.
这项工作描述了用于制备锡掺杂氧化铟纳米晶体分散体的连续注射协议的可扩展性过程。从合成和加工开始的不同程度的操作,也与光学响应的调节有关(考虑到紫外和近红外吸收与可见光透明度的特殊组合),使得这些材料具有令人难以置信的多功能性。但最吸引人的特点之一是通过化学或合成后掺杂来调制其电荷载流子密度,就像核壳材料的情况一样,扩展了核成分的性能。此外,这类材料的胶体性质便于溶液加工,使其能够在当前薄膜基础技术的不同应用中广泛使用。因此,推进实验室规模的合成以在不损失任何质量的情况下正确满足商业制造要求非常重要。均匀性对于工业应用至关重要,可确保可预测的性能并便于将这些纳米颗粒集成到光电器件中。这里开发的方法实现了从毫克级到克级产品质量产出的转变,同时在粒径分布、形态、结晶度和光学性质方面保持稳定。这项研究为可扩展生产具有一致性质的金属氧化物纳米颗粒建立了一个强大的框架,提高了它们在光电子应用中广泛使用的可行性。