Department of Chemistry and Ilse Katz Institute for Nanoscale Science and Technology, Ben-Gurion University of the Negev, Beer-Sheva, 8410501, Israel.
Discipline of Chemistry, IIT Gandhinagar, Palaj, Gandhinagr-, 382355, Gujarat, India.
ChemSusChem. 2023 May 19;16(10):e202300621. doi: 10.1002/cssc.202300621.
Invited for this month's cover are the groups of Menny Shalom at the Ben-Gurion University of the Negev, Israel and Dr. Biswajit Mondal at Indian Institute of Technology Gandhinagar, India. The image shows the connection between two half-cells: an electron transfer-mediated [(2,2,6,6-tetramethyl-1-piperidin-1-yl)oxyl] (TEMPO)-catalyzed benzylamine oxidation at the anode and a proton-coupled electron transfer at the cathode for hydrogen generation. The difference in pH dependence of the anodic and cathodic processes enables hybrid water electrolysis at low cell potential (∼1.0 V) by adjusting only the pH value of the electrolytic medium. The Research Article itself is available at 10.1002/cssc.202202271.
受邀为本月封面的是以色列内盖夫本古里安大学的 Menny Shalom 小组和印度甘地讷格尔印度理工学院的 Biswajit Mondal 博士。该图像显示了两个半电池之间的连接：在阳极处，电子转移介导的 [(2,2,6,6-四甲基-1-哌啶-1-基)氧]（TEMPO）催化的苄胺氧化，以及阴极处的质子耦合电子转移用于产氢。阳极和阴极过程的 pH 依赖性差异使得通过仅调整电解质介质的 pH 值即可在低电池电势（约 1.0 V）下进行混合水电解。研究文章本身可在 10.1002/cssc.202202271 上获得。
