Center of Eco-Material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, 730000, Lanzhou, PR China.
Shandong Xinna Superhydrophobic New Materials Co. Ltd., 265402, Yantai, PR China.
Nat Commun. 2023 May 19;14(1):2862. doi: 10.1038/s41467-023-38678-0.
Superhydrophobic coatings are expected to solve the rain attenuation issue of 5G radomes. However, it is very challenging to design and construct such superhydrophobic coatings with good impalement resistance, mechanical robustness, and weather resistance, which remains as one of the main bottlenecks hindering their practical applications. Here, we report the design of superhydrophobic coatings with all these merits mentioned above by spray-coating a suspension of adhesive/fluorinated silica core/shell microspheres onto substrates. The core/shell microspheres are formed by phase separation of the adhesive and adhesion between the adhesive and fluorinated silica nanoparticles. The coatings have an approximately isotropic three-tier hierarchical micro-/micro-/nanostructure, a dense but rough surface at the nanoscale, and chemically inert composition with low surface energy. Consequently, the coatings show excellent impalement resistance, mechanical robustness and weather resistance compared with previous studies, and the mechanisms are revealed. Furthermore, we realize large-scale preparation, extension, and practical application of the coatings for efficiently preventing rain attenuation of 5G/weather radomes. By taking these advantages, we believe that the superhydrophobic coatings have great application potential and market prospect. The findings here will boost preparation and real-world applications of superhydrophobic coatings.
超疏水涂层有望解决 5G 天线罩的雨衰减问题。然而,设计和构建具有良好耐刺穿性、机械鲁棒性和耐候性的这种超疏水涂层极具挑战性,这仍然是阻碍其实际应用的主要瓶颈之一。在这里,我们通过喷涂粘性/氟化硅核/壳微球的悬浮液在基底上报告了具有所有上述优点的超疏水涂层的设计。核/壳微球是由粘性的相分离和粘性与氟化硅纳米粒子之间的粘附形成的。该涂层具有近似各向同性的三级微/微/纳米结构,纳米尺度上具有密集但粗糙的表面,以及化学惰性组成和低表面能。因此,与先前的研究相比,涂层表现出优异的耐刺穿性、机械鲁棒性和耐候性,并且揭示了其机制。此外,我们实现了涂层的大规模制备、扩展和实际应用,有效地防止了 5G/天气雷达天线罩的雨衰减。凭借这些优势,我们相信超疏水涂层具有巨大的应用潜力和市场前景。本研究的结果将推动超疏水涂层的制备和实际应用。