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TTS软件包:应用时间-温度叠加原理的计算工具。

TTS package: Computational tools for the application of the Time Temperature Superposition principle.

作者信息

Meneses Antonio, Naya Salvador, Francisco-Fernández Mario, López-Beceiro Jorge, Gracia-Fernández Carlos, Tarrío-Saavedra Javier

机构信息

Universidad Nacional de Chimborazo, Riobamba, Ecuador.

CITIC, Grupo MODES, Departamento de Matemáticas, Escola Politécnica de Enxeñaría de Ferrol, Universidade da Coruña, Ferrol, Spain.

出版信息

Heliyon. 2023 May 4;9(5):e15816. doi: 10.1016/j.heliyon.2023.e15816. eCollection 2023 May.

DOI:10.1016/j.heliyon.2023.e15816
PMID:37215836
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10192834/
Abstract

The TTS package has been developed in R software to predict the mechanical properties of viscoelastic materials, at short and long observation times/frequencies by applying the Time Temperature Superposition (TTS) principle. TTS is a physical principle used in material science to estimate mechanical properties beyond the experimental range of observed times/frequencies by shifting data curves obtained at other temperatures relative to a reference temperature in the dataset. It is a methodology related to accelerated life-tests and reliability, whereas the TTS library is one of the first open source computational tool to apply the TTS principle. This R package provides free computational tools to obtain master curves that characterize materials from a thermal-mechanical approach. The TTS package also proposes, implements and explains our own method to obtain the shift factors and the master curve in a TTS analysis, based on horizontal shifting of the first derivative function of viscoelastic properties. This procedure provides shift factors estimates and smooth master curve estimates using B-spline fitting, in a fully automatic way, without assuming any parametric expression. Williams-Landel-Ferry (WLF) and Arrhenius TTS parametric models are also implemented in the TTS package. They can be fitted from shifts obtained by the our first derivative based method.

摘要

TTS软件包是用R软件开发的,用于通过应用时间-温度叠加(TTS)原理来预测粘弹性材料在短时间和长时间观察时间/频率下的力学性能。TTS是材料科学中使用的一种物理原理,通过将在其他温度下获得的数据曲线相对于数据集中的参考温度进行移位,来估计超出观察时间/频率实验范围的力学性能。它是一种与加速寿命测试和可靠性相关的方法,而TTS库是应用TTS原理的首批开源计算工具之一。这个R软件包提供了免费的计算工具,以从热机械方法获得表征材料的主曲线。TTS软件包还提出、实现并解释了我们自己的方法,即在TTS分析中基于粘弹性特性的一阶导数函数的水平移位来获得移位因子和主曲线。此过程使用B样条拟合以全自动方式提供移位因子估计值和平滑的主曲线估计值,而无需假设任何参数表达式。Williams-Landel-Ferry(WLF)和Arrhenius TTS参数模型也在TTS软件包中实现。它们可以根据通过我们基于一阶导数的方法获得的移位进行拟合。

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