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用于自驱动收集漂浮粘性油的超疏水/超亲油聚二甲基硅氧烷/二氧化硅气凝胶织物收集装置

Superhydrophobic/Superoleophilic PDMS/SiO Aerogel Fabric Gathering Device for Self-Driven Collection of Floating Viscous Oil.

作者信息

Liu Feng, Di Xin, Sun Xiaohan, Wang Xin, Yang Tinghan, Wang Meng, Li Jian, Wang Chengyu, Li Yudong

机构信息

Key Laboratory of Bio-Based Material Science & Technology of Ministry of Education, Northeast Forestry University, Harbin 150040, China.

State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150001, China.

出版信息

Gels. 2023 May 12;9(5):405. doi: 10.3390/gels9050405.

Abstract

The persistent challenge of removing viscous oil on water surfaces continues to pose a major concern and requires immediate attention. Here, a novel solution has been introduced in the form of a superhydrophobic/superoleophilic PDMS/SiO aerogel fabric gathering device (SFGD). The SFGD is based on the adhesive and kinematic viscosity properties of oil, enabling self-driven collection of floating oil on the water surface. The SFGD is able to spontaneously capture the floating oil, selectively filter it, and sustainably collect it into its porous fabric interior through the synergistic effects of surface tension, gravity, and liquid pressure. This eliminates the need for auxiliary operations such as pumping, pouring, or squeezing. The SFGD demonstrates exceptional average recovery efficiencies of 94% for oils with viscosities ranging from 10 to 1000 mPa·s at room temperature, including dimethylsilicone oil, soybean oil, and machine oil. With its facile design, ease of fabrication, high recovery efficiency, excellent reclaiming capabilities, and scalability for multiple oil mixtures, the SFGD represents a significant advancement in the separation of immiscible oil/water mixtures of various viscosities and brings the separation process one step closer to practical application.

摘要

去除水面上粘性油的持续挑战仍然是一个主要问题,需要立即引起关注。在此,一种新型解决方案以超疏水/超亲油的聚二甲基硅氧烷/二氧化硅气凝胶织物收集装置(SFGD)的形式被引入。SFGD基于油的粘性和运动粘度特性,能够实现水面上漂浮油的自驱动收集。SFGD能够自发捕获漂浮油,选择性过滤,并通过表面张力、重力和液体压力的协同作用将其可持续收集到其多孔织物内部。这消除了诸如泵送、倾倒或挤压等辅助操作的需要。在室温下,SFGD对粘度范围为10至1000 mPa·s的油,包括二甲基硅油、大豆油和机油,平均回收效率高达94%。凭借其简便的设计、易于制造、高回收效率、出色的回收能力以及对多种油混合物的可扩展性,SFGD代表了在分离各种粘度的不混溶油/水混合物方面的重大进展,并使分离过程更接近实际应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f646/10217856/edb695227592/gels-09-00405-g001.jpg

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