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具有优异油/有机溶剂吸附性能和热性能的纺织废纤维气凝胶的制备

Fabrication of Textile Waste Fibers Aerogels with Excellent Oil/Organic Solvent Adsorption and Thermal Properties.

作者信息

Dong Chunlei, Hu Yangzhao, Zhu Yuxuan, Wang Jiale, Jia Xuerui, Chen Jianbing, Li Jingliang

机构信息

Research Centre for Non-Metallic Materials, Chizhou University, Chizhou 247000, China.

Institute for Frontier Materials, Deakin University, Geelong, VIC 3200, Australia.

出版信息

Gels. 2022 Oct 21;8(10):684. doi: 10.3390/gels8100684.

Abstract

In recent years, the treatment of textile waste has attracted more and more attention around the world. The reuse of textile waste can contribute to the reduction of carbon emissions and the sustainable development of the economy. Herein, we proposed a facile and cost-effective approach to fabricating aerogel by using textile waste fibers as the matrix and polyvinyl alcohol (PVA) and glutaraldehyde (GA) as crosslinking agents. After being modified with methyltrimethoxysilane (MTMS) via chemical vapor deposition, both the interior and exterior of the textile waste aerogels exhibit a hydrophobic property with a water contact angle of up to 136.9° ± 2.3°. A comprehensive investigation of the structure, thermal properties, mechanical properties and oil absorption capacity of this aerogel shows its potential for building insulation and oil spill cleanup. The textile waste fibers aerogels have low density and high porosity, good thermal stability and outstanding heat insulation properties (K = 0.049-0.061 W/m·K). With a maximum oil absorption value of 26.9 ± 0.6 g/g and rapid and effective oil/water mixture separation, the aerogel exhibits competitive commercial application value.

摘要

近年来,纺织废料的处理在全球范围内受到越来越多的关注。纺织废料的再利用有助于减少碳排放和经济的可持续发展。在此,我们提出了一种简便且经济高效的方法,以纺织废料纤维为基质,聚乙烯醇(PVA)和戊二醛(GA)为交联剂来制备气凝胶。通过化学气相沉积用甲基三甲氧基硅烷(MTMS)进行改性后,纺织废料气凝胶的内部和外部均呈现出疏水性,水接触角高达136.9°±2.3°。对这种气凝胶的结构、热性能、力学性能和吸油能力进行的全面研究表明,其在建筑保温和溢油清理方面具有潜力。纺织废料纤维气凝胶具有低密度和高孔隙率、良好的热稳定性和出色的隔热性能(K = 0.049 - 0.061 W/m·K)。该气凝胶的最大吸油值为26.9±0.6 g/g,能快速有效地分离油/水混合物,具有具有竞争力的商业应用价值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7501/9601950/c0104e4d617d/gels-08-00684-g001.jpg

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