• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

使用磁性壳聚糖/纤维素-Fe(III)复合材料作为生物吸附剂从水溶液中吸附去除重金属

Adsorptive Elimination of Heavy Metals from Aqueous Solution Using Magnetic Chitosan/Cellulose-Fe(III) Composite as a Bio-Sorbent.

作者信息

Khalid Aina Mardhia, Hossain Md Sohrab, Khalil Nor Afifah, Zulkifli Muzafar, Arafath Md Azharul, Shaharun Maizatul Shima, Ayub Rashid, Ahmad Yahaya Ahmad Naim, Ismail Norli

机构信息

School of Industrial Technology, Universiti Sains Malaysia (USM), George Town 11800, Malaysia.

Department of Fundamental and Applied Sciences, Faculty of Science and Information Technology, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia.

出版信息

Nanomaterials (Basel). 2023 May 10;13(10):1595. doi: 10.3390/nano13101595.

DOI:10.3390/nano13101595
PMID:37242012
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10220609/
Abstract

Magnetic chitosan/cellulose nanofiber-Fe(III) [M-Ch/CNF-Fe(III)] composites were isolated for the elimination of Cr(VI), Cu(II), and Pb(II) from aqueous solution. Various analytical methods, such as field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction analysis (XRD), and thermogravimetric analysis (TGA) were employed to determine the morphological, physicochemical, and thermal properties of the isolated M-Ch/CNF-Fe(III) composites. It was found that the M-Ch/CNF-Fe(III) composites were porous materials, and they have the potential to be implemented as an adsorbent for heavy metals removal. The adsorption efficiency of M-Ch/CNF-Fe(III) composites was determined for Cr(VI), Cu(II), and Pb(II) elimination with changing pH (pH 1.0-8.0), adsorbent doses (0.05-1.0 g), time (15-90 min), and temperature (28-80 °C). In addition, isothermal and kinetics studies were conducted to assess the adsorption behavior and mass transfer phenomena of M-Ch/CNF-Fe(III) composites as an adsorbent for Cr(VI), Cu(II) and Pb(II) elimination from aqueous solution. The outcomes of the present study reveal that the M-Ch/CNF-Fe(III) composites could be utilized as an adsorbent for the Cr(VI), Cu(II), and Pb(II) elimination from industrial effluents.

摘要

制备了磁性壳聚糖/纤维素纳米纤维-Fe(III)[M-Ch/CNF-Fe(III)]复合材料，用于去除水溶液中的Cr(VI)、Cu(II)和Pb(II)。采用多种分析方法，如场发射扫描电子显微镜(FE-SEM)、透射电子显微镜(TEM)、傅里叶变换红外光谱(FT-IR)、X射线衍射分析(XRD)和热重分析(TGA)，来测定分离得到的M-Ch/CNF-Fe(III)复合材料的形态、物理化学和热性能。结果发现，M-Ch/CNF-Fe(III)复合材料是多孔材料，具有作为重金属去除吸附剂的潜力。测定了M-Ch/CNF-Fe(III)复合材料在pH值变化(pH 1.0-8.0)、吸附剂剂量(0.05-1.0 g)、时间(15-90分钟)和温度(28-80℃)条件下去除Cr(VI)、Cu(II)和Pb(II)的吸附效率。此外，还进行了等温吸附和动力学研究，以评估M-Ch/CNF-Fe(III)复合材料作为吸附剂从水溶液中去除Cr(VI)、Cu(II)和Pb(II)的吸附行为和传质现象。本研究结果表明，M-Ch/CNF-Fe(III)复合材料可作为吸附剂用于去除工业废水中的Cr(VI)、Cu(II)和Pb(II)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/18e6a1d18c41/nanomaterials-13-01595-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/a00d4bcda8cf/nanomaterials-13-01595-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/9fb51ccba561/nanomaterials-13-01595-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/7ddfcd750217/nanomaterials-13-01595-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/43a1b8acd448/nanomaterials-13-01595-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/2dc7fdb7dccf/nanomaterials-13-01595-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/6ccab1d80ef9/nanomaterials-13-01595-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/18e6a1d18c41/nanomaterials-13-01595-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/a00d4bcda8cf/nanomaterials-13-01595-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/9fb51ccba561/nanomaterials-13-01595-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/7ddfcd750217/nanomaterials-13-01595-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/43a1b8acd448/nanomaterials-13-01595-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/2dc7fdb7dccf/nanomaterials-13-01595-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/6ccab1d80ef9/nanomaterials-13-01595-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/baa5/10220609/18e6a1d18c41/nanomaterials-13-01595-g007.jpg

相似文献

1
Adsorptive Elimination of Heavy Metals from Aqueous Solution Using Magnetic Chitosan/Cellulose-Fe(III) Composite as a Bio-Sorbent.使用磁性壳聚糖/纤维素-Fe(III)复合材料作为生物吸附剂从水溶液中吸附去除重金属
Nanomaterials (Basel). 2023 May 10;13(10):1595. doi: 10.3390/nano13101595.
2
Isolation and Characterization of Magnetic Oil Palm Empty Fruits Bunch Cellulose Nanofiber Composite as a Bio-Sorbent for Cu(II) and Cr(VI) Removal.磁性油棕空果串纤维素纳米纤维复合材料作为去除铜（II）和铬（VI）的生物吸附剂的分离与表征
Polymers (Basel). 2020 Dec 30;13(1):112. doi: 10.3390/polym13010112.
3
Batch adsorption studies on surface tailored chitosan/orange peel hydrogel composite for the removal of Cr(VI) and Cu(II) ions from synthetic wastewater.批次吸附研究表明，壳聚糖/橙皮水凝胶复合材料经表面修饰后，可从合成废水中去除 Cr(VI) 和 Cu(II) 离子。
Chemosphere. 2021 May;271:129415. doi: 10.1016/j.chemosphere.2020.129415. Epub 2021 Jan 2.
4
Performance of ceria/iron oxide nano-composites based on chitosan as an effective adsorbent for removal of Cr(VI) and Co(II) ions from aqueous systems.基于壳聚糖的铈/氧化铁纳米复合材料作为一种有效的吸附剂，用于从水体系中去除 Cr(VI)和 Co(II)离子的性能。
Environ Sci Pollut Res Int. 2018 Sep;25(27):27059-27073. doi: 10.1007/s11356-018-2594-x. Epub 2018 Jul 17.
5
Mechanism of Cr(VI) removal by magnetic greigite/biochar composites.磁性针铁矿/生物炭复合材料去除 Cr(VI)的机理。
Sci Total Environ. 2020 Jan 15;700:134414. doi: 10.1016/j.scitotenv.2019.134414. Epub 2019 Sep 12.
6
Cu-Fe embedded cross-linked 3D hydrogel for enhanced reductive removal of Cr(VI): Characterization, performance, and mechanisms.铜铁嵌入交联 3D 水凝胶增强六价铬的还原去除：特性、性能和机制。
Chemosphere. 2021 Oct;280:130663. doi: 10.1016/j.chemosphere.2021.130663. Epub 2021 May 3.
7
Magnetic layered double hydroxide composite as new adsorbent for efficient Cu (II) and Ni (II) ions removal from aqueous samples: Adsorption mechanism investigation and parameters optimization.磁性层状双氢氧化物复合材料作为新型吸附剂，用于从水样中高效去除 Cu(II) 和 Ni(II) 离子：吸附机制研究与参数优化。
J Environ Manage. 2023 Mar 1;329:117009. doi: 10.1016/j.jenvman.2022.117009. Epub 2022 Dec 17.
8
A novel cellulose hydrogel coating with nanoscale Fe for Cr(VI) adsorption and reduction.一种新型纤维素水凝胶涂层，具有纳米级 Fe，用于 Cr(VI)的吸附和还原。
Sci Total Environ. 2020 Jul 15;726:138625. doi: 10.1016/j.scitotenv.2020.138625. Epub 2020 Apr 13.
9
Salicylaldehyde derivative of nano-chitosan as an efficient adsorbent for lead(II), copper(II), and cadmium(II) ions.纳米壳聚糖水杨醛衍生物作为一种高效的铅(II)、铜(II)和镉(II)离子吸附剂。
Int J Biol Macromol. 2020 Mar 15;147:643-652. doi: 10.1016/j.ijbiomac.2020.01.091. Epub 2020 Jan 11.
10
Preparation of biochar-interpenetrated iron-alginate hydrogel as a pH-independent sorbent for removal of Cr(VI) and Pb(II).制备生物炭互穿海藻酸铁水凝胶作为一种对pH不敏感的吸附剂用于去除Cr(VI)和Pb(II)。
Environ Pollut. 2021 Oct 15;287:117303. doi: 10.1016/j.envpol.2021.117303. Epub 2021 May 10.

引用本文的文献

1
Thermodynamic Aspects of Ion Exchange Properties of Bio-Resins from Phosphorylated Cellulose Fibers.磷酸化纤维素纤维生物树脂离子交换性能的热力学方面
Polymers (Basel). 2025 Jul 24;17(15):2022. doi: 10.3390/polym17152022.
2
Application of andesite and hydrolyzed poly acrylonitrile andesite composite for adsorption of Al(III), Fe(III), CHSH, and HS form aqueous solutions.安山岩与水解聚丙烯腈安山岩复合材料在从水溶液中吸附铝（III）、铁（III）、硫醇和硫化氢方面的应用。
Sci Rep. 2025 Jul 20;15(1):26364. doi: 10.1038/s41598-025-09497-8.
3
Development of a Treatment System of Water with Cr (VI) Through Models Using Biomass with Iron Chloride.

本文引用的文献

1
Economic and fast electro-flotation extraction of heavy metals from wastewater.从废水中经济快速地电浮选提取重金属
Environ Technol. 2022 Oct 2:1-10. doi: 10.1080/09593330.2022.2120831.
2
Facile Fabrication of Cellulose Nanofibrils/Chitosan Beads as the Potential pH-Sensitive Drug Carriers.纤维素纳米原纤维/壳聚糖珠作为潜在pH敏感药物载体的简易制备
Polymers (Basel). 2022 Jun 4;14(11):2286. doi: 10.3390/polym14112286.
3
Extraction of Nanocellulose for Eco-Friendly Biocomposite Adsorbent for Wastewater Treatment.用于废水处理的环保型生物复合吸附剂的纳米纤维素提取
通过使用含氯化铁生物质的模型开发六价铬水处理系统
Toxics. 2025 Mar 20;13(3):230. doi: 10.3390/toxics13030230.
4
Adsorption kinetics and mechanisms of nano chitosan coated cotton fiber for the removal of heavy metals from industrial effluents.纳米壳聚糖包覆棉纤维对工业废水中重金属的吸附动力学及机理
Heliyon. 2025 Feb 22;11(4):e42932. doi: 10.1016/j.heliyon.2025.e42932. eCollection 2025 Feb 28.
5
Recent Progress on the Adsorption of Heavy Metal Ions Pb(II) and Cu(II) from Wastewater.废水中重金属离子Pb(II)和Cu(II)吸附的研究进展
Nanomaterials (Basel). 2024 Jun 16;14(12):1037. doi: 10.3390/nano14121037.
Polymers (Basel). 2022 Apr 30;14(9):1852. doi: 10.3390/polym14091852.
4
Biosorption of Cr(VI) Using Cellulose Nanocrystals Isolated from the Waterless Pulping of Waste Cotton Cloths with Supercritical CO: Isothermal, Kinetics, and Thermodynamics Studies.使用从废棉布无水制浆中分离得到的纤维素纳米晶体通过超临界CO₂对Cr(VI)进行生物吸附：等温、动力学和热力学研究
Polymers (Basel). 2022 Feb 23;14(5):887. doi: 10.3390/polym14050887.
5
Functionalized dual modification of covalent organic framework for efficient and rapid trace heavy metals removal from drinking water.功能化双修饰共价有机框架用于从饮用水中高效快速去除痕量重金属。
Chemosphere. 2022 Mar;290:133215. doi: 10.1016/j.chemosphere.2021.133215. Epub 2021 Dec 14.
6
Interactions and effects of microplastics with heavy metals in aquatic and terrestrial environments.微塑料与重金属在水-陆环境中的相互作用与影响。
Environ Pollut. 2021 Dec 1;290:118104. doi: 10.1016/j.envpol.2021.118104. Epub 2021 Sep 3.
7
Critical review on hazardous pollutants in water environment: Occurrence, monitoring, fate, removal technologies and risk assessment.水环境中危险污染物的批判性回顾：发生、监测、命运、去除技术和风险评估。
Sci Total Environ. 2021 Nov 25;797:149134. doi: 10.1016/j.scitotenv.2021.149134. Epub 2021 Jul 23.
8
Recycling Waste Cotton Cloths for the Isolation of Cellulose Nanocrystals: A Sustainable Approach.回收废棉布用于分离纤维素纳米晶体：一种可持续的方法。
Polymers (Basel). 2021 Feb 19;13(4):626. doi: 10.3390/polym13040626.
9
Isolation and Characterization of Magnetic Oil Palm Empty Fruits Bunch Cellulose Nanofiber Composite as a Bio-Sorbent for Cu(II) and Cr(VI) Removal.磁性油棕空果串纤维素纳米纤维复合材料作为去除铜（II）和铬（VI）的生物吸附剂的分离与表征
Polymers (Basel). 2020 Dec 30;13(1):112. doi: 10.3390/polym13010112.
10
Treatment of Palm Oil Refinery Effluent Using Tannin as a Polymeric Coagulant: Isotherm, Kinetics, and Thermodynamics Analyses.使用单宁作为聚合混凝剂处理棕榈油精炼废水：等温线、动力学和热力学分析
Polymers (Basel). 2020 Oct 14;12(10):2353. doi: 10.3390/polym12102353.