Li Jing, Ren Hongjiang, Li Jiangtao
The Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province, Key Laboratory of Chemistry of New Material of Functional Inorganic Composites, School of Chemical Engineering, Xi'an University, Xi'an, Shaanxi, China.
J Fluoresc. 2024 Jan;34(1):333-339. doi: 10.1007/s10895-023-03282-4. Epub 2023 May 30.
In this work, benzimidazole (Hbim) and Cu(II) ions ligands were chosen as building blocks to produce a novel Cu(II) compound (CP) based on {CuO}cluster, namely, [CuOCl(Hbim)]·n(HO)·2n(EtOH) (1). The investigation of SCXRD reveals that the CP 1 is a separated 0D structure based on tetrahedral {CuO} clusters. Furthermore, this supramolecular frame displayed superior photocatalytic effect on the photodegradation of MB under UV light irradiation.
在本工作中，选择苯并咪唑（Hbim）和铜（II）离子配体作为构建单元，以制备一种基于{CuO}簇的新型铜（II）化合物（CP），即[CuOCl(Hbim)]·n(H₂O)·2n(EtOH)（1）。单晶X射线衍射分析表明，CP 1是基于四面体{CuO}簇的离散零维结构。此外，这种超分子框架在紫外光照射下对亚甲基蓝的光降解表现出优异的光催化效果。
