Hussain Fayyaz Salih, Memon Najma, Khatri Zeeshan
National Center of Excellence in Analytical Chemistry, University of Sindh, Jamshoro 76080, Sindh, Pakistan.
Department of Textile Engineering, Mehran University of Engineering and Technology, Jamshoro 76062, Pakistan.
ACS Omega. 2023 May 18;8(21):18617-18625. doi: 10.1021/acsomega.3c00492. eCollection 2023 May 30.
Metallic or metal oxide-based nanoparticles have the potential to inactivate viruses. Among various metals, copper has shown edge over others. One of the rapidly evolving areas is to combine nanoscience for production of self-sanitizing antiviral surfaces. In this study, we designed antiviral-coated fabrics to combat the spread of viruses. Copper oxide nanoparticles were sonochemically synthesized and subsequently deposited using the dip-coat process to modify the surface of fabric. The morphology and structure of uncoated and coated fabrics were examined by scanning electron microscopy, X-ray diffraction, FTIR, and elemental analysis. The findings show that small, agglomerated rugby ball structures made of copper oxide (CuO) nanoparticles (16 ± 1.6 nm, according to the Scherrer equation) develop on the surface of fabric, resulting in nano-embossing and a hydrophobic (contact angle > 140°) surface. The CuO-coated fabric yielded the maximum zone of inhibition for antibacterial activity. The virucidal activity (against human adenovirus-B) of CuO nanoparticle-fabricated fabric against adenovirus shows decreased 99.99% according to the ISO 18184 testing standard. With the dip and dry approach, any textile industry can use the simple coating procedure without having to change its textile operations. This fabric can be widely used in the face mask, clothing, bedding, and aprons, and the coating remains efficient over more than 25 washes.
金属或金属氧化物基纳米粒子具有使病毒失活的潜力。在各种金属中,铜已显示出比其他金属更具优势。一个快速发展的领域是将纳米科学结合起来用于生产自消毒抗病毒表面。在本研究中,我们设计了抗病毒涂层织物以对抗病毒传播。通过超声化学合成氧化铜纳米粒子,随后采用浸涂工艺进行沉积以修饰织物表面。通过扫描电子显微镜、X射线衍射、傅里叶变换红外光谱和元素分析对未涂层和涂层织物的形态和结构进行了检查。研究结果表明,由氧化铜(CuO)纳米粒子(根据谢乐方程为16±1.6纳米)构成的小的、团聚的橄榄球形状结构在织物表面形成,导致纳米压花和疏水(接触角>140°)表面。CuO涂层织物产生了最大的抗菌活性抑制区。根据ISO 18184测试标准,CuO纳米粒子制成的织物对腺病毒的杀病毒活性(针对人腺病毒-B)显示降低了99.99%。采用浸涂和干燥方法,任何纺织行业都可以使用这种简单的涂层工艺,而无需改变其纺织操作。这种织物可广泛用于口罩(面罩)、服装、床上用品和围裙,并且涂层在超过25次洗涤后仍保持有效。